HVOF喷涂纳米WC-17Co和超细WC-17Co涂层高温摩擦磨损行为.pdfVIP

第十一届国际热喷涂研讨会论文 (ITSS’2008) 第十二届全国热喷涂年会论文 (CNTSC’2008) HVOF喷涂纳米WC-17Co和超细WC-17Co涂层 高温摩擦磨损行为 [1] [2] [2] [1] [2] 陈辉 ，苟国庆 ，涂铭旌 ，刘艳 (1.四川大学材料学院， 四川 成都 610065； 2. 西南交通大学材料学院，四川 成都 610031) ① 摘 要：本文利用超音速火焰喷涂技术制备了纳米WC-17Co涂层以及超细WC-17Co涂层。研究了纳米喷涂粉末和 超细喷涂粉末的微观组织结构。采用 GCR15 作为摩擦副测试研究了环境温度为 600℃时涂层的高温滑动摩擦磨损行 为。研究表明，在纳米喷涂粉末中，WC粒子尺寸细小、均匀。尺寸在50nm-500nm之间，并且在WC粒子表面有很多 2-5nm 之间的纳米结构晶粒。这些晶粒在超音速喷涂条件下可以作为晶核，启动细化晶粒的作用，对纳米喷涂层的 形成有利。在高温磨损环境下，纳米涂层的综合耐滑动磨损性能优于超细涂层，并且纳米涂层的抗高温断裂性能优 于超细涂层。纳米涂层的高温磨损失效机理以磨粒磨损为主，伴随有黏着磨损。超细涂层的高温磨损失效机理以低 延性开裂和黏着磨损为主，伴随有磨粒磨损。 关键词：纳米结构；HVOF；WC-17Co；高温磨损 Friction and wear behavior of HVOF nanostructured and ultra-fine WC-17Co coatings CHEN Hui [1] [2] ，GOU Guo-qing [2] ，TU Mingjing[1] ，LIU Yan [2] (1. Institute of Materials Science and Engineering, Sichuan University, Chengdu 610065,china; 2. Institute of Materials Science and Engineering, Southwest Jiaotong Univesity, Chengdu 610031 ，China) Abstract ：Nanostructured and ultra-fine WC-Co coatings have been obtained by means of High Velocity Oxygen Flame (HVOF) technique. The nano-structure and microstructure of the powders were analyzed. The wear resistance at elevated temperature (600℃) of the resulting coatings was compared using GCr15 as counterparts in sliding wear tests. The results show that the sizes of WC particle are about 50-500nm. Finer sub-structures of 2-5nm were found to distribute evenly on the nanostructured WC particle surface. These sub-particles can act as crystallizing nucleus and make the grains much finer during the HVOF spraying process, which is beneficial to the formation of the