镍基合金C-276在超临界水中的腐蚀行为的研究.pdfVIP

The 6th China Corrosion Conference The Corrosion Behavior of Hastelloy C-276 in Supercritical Water 1,2 1 1 2 Yanxin QIAO , Feihua LIU , Ai REN , Yugui ZHENG 1Suzhou Nuclear Power Research Institute, Suzhou, Jiangsu, China, 215004 2Institute of Metal Research, Chinese Academy of Sciences, Shenyang, Liaoning, China, 110016 Abstract: The corrosion behavior of Hastelloy C-276 exposed in supercritical water (SCW) at 500 ℃/25MPa was investigated by means of gravimetry, scanning electron microscope (SEM) equipped with an energy-dispersive X-ray spectrometer (EDX) and X –ray diffraction (XRD). The results showed that the growth mechanism of oxide film formed on C-276 in SCW obey the parabola law. The oxide film formed in SCW mainly consists of Cr, Ni and O. Exposed time has no effect on the composition of oxide film. The oxide film formed on Hastelloy C-276 with dual layer structure, mainly consisting of a Ni rich outer layer and a Cr rich inner compact layer, developed on tested material in SCW. The quantity of oxide particles decorated on outer oxide layer increase with the increasing of exposed time. Keywords: Supercritical water coolant reactor; Corrosion; Oxidation; SEM 镍基合金 C-276 在超临界水中的腐蚀行为研究 乔岩欣1,2 1 1 2 ，刘飞华 ，任爱 ，郑玉贵 1 苏州热工研究院，江苏，苏州，215004 2 中国科学院金属研究所，辽宁，沈阳，110016 摘 要：利用氧化增重法对镍基合金C-276 在500℃/25MPa 超临界纯中的氧化动力学行为进行了研究， 并利用扫描电镜（SEM ）和X 射线衍射（XRD ）对材料表面氧化膜的成分和结构进行了分析。结果表 明：C-276 合金在500℃/25MPa 的超临界水中的氧化动力学曲线遵守抛物线