污水中溶解性有机质对土壤吸附四溴双酚A的影响.pdfVIP

农业环境科学学报 2008，27(6)：2222—2226 JournalofAgro—EnvironmentScience 污水中溶解性有机质对土壤吸附四溴双酚A的影响 孙兆海，毛 丽，冯 政 ，余益军，于红霞 (污染控制与资源化研究国家重点实验室，南京大学环境学院，江苏 南京 210093) 摘 要：采用批量平衡实验方法，研究了城市污水处理厂进水和出水中的溶解性有机质(D0M)对四溴双酚A(TBBPA)在3种土壤 中吸附行为的影响。结果表明，TBBPA在 3种土壤中的分配系数为20．0—465．7L·kg～，pH和有机质含量是影响土壤吸附TBBPA的 重要因素。DOM对土壤吸附TBBPA的影响与DOM添加浓度和土壤性质有关。DOM．的加入没有抑制TBBPA在潮土和草甸棕壤中 的吸附，但显著抑NTTBBPA在灰色石灰土中的吸附。DOM对土壤吸附TBBPA的影响主要是TBBPA与DOM在土壤中的累积吸 附效应和溶液pH等共同作用的结果。 关键词：四溴双酚A；溶解性有机质；吸附；污水；土壤 中图分类号：X53；X131．3 文献标识码：A 文章编号：1672—2043(2008)06—2222—05 EffectsofDissolvedOrganicM atterfrom W astewateronSorptionofTetrabromobisphenolA toSoils SUNZhao—hal，MAOLi，FENGZheng，YUYi-jun，YUHong-xia (StateKeyLaboratoryofPollutionControlandResourceReuse，SchooloftheEnvironment，NamingUniversity，Nanjing210093，China) Abstract：SorptionoftetrabromobisphenolA(TBBPA)onsoilinf1ueneesthefateandtransportofTBBPAinenvironment，andthesorptionpro— cessonsoilmaybecomplicatedinthepresenceofdissolvedorganicmatter(DOM)．Usingbatchequilibriumexperiments，theeffectsofDOM isolatedfrom theinfluentandeffluentofamunicipalwastewatertreatmentplantonthesorptionofTBBPAtothreesoilswereinvestigated．The resultsshowedthatthedistributioncoefficientsofTBBPAinthethreesoilsrangedrfom 20．0to465．7L·kg～．andthatthepHandorganicmatter contentofthesoilsplayedanimportantroleinthesorptionofTBBPA．TheeffectsofDOM onthesorptionwerestronglyrelatedtotheconeentra- tionoftheDOMandthepropertiesofthesoils．WhilethepresenceofDOMdidnotinhibitthesorptionofTBBPAtothefluvo-aquicsoil(sandy loam)andthemeadowbrownsoil(1oamyclay)，itsignificantlysuppressedthesorptionofTBBPAtothegreylimesoil(siltloam)．Theimpactsof theDOMonthesorptionofTBBPAweremainlycontrolledbythecumulativesorptioneffectandthesolutionpH．Theresultsofthisworkwould helptOunderstandthesorptionandtransportbehaviorsofTBBPAinsoilsirrigatedwithwastewater． Keywords：tetrabromobisphenolA；dissolvedorganicmatter；sorption；wastewater；soll 水资源短缺是全世界面临的严峻问题，为解决这 DOM对有机污染物吸附的影响不仅取决于土壤和 一 问