邻苯二甲酸酯类化合物在茶叶中的存在及其来源与探讨.pdfVIP

邻苯二甲酸酯类化合物在茶叶中的存在及其来源探讨 尹 鹏 ，陈红平，刘 新，潘 蓉，张明露 （中国农业科学院茶叶研究所，浙江杭州 310008 ） 摘要：邻苯二甲酸酯类化合物具有“三致”（致癌、致畸、致突变）作用，是内分泌干扰物。另外，PAEs 还具有类雌激素效应，可能 引起男性内分泌紊乱，导致精子数量减少。基于 PAEs 对人类健康造成的危害，世界各国已将其列为优先控制污染物。国内外学者在 研究茶叶香气或挥发性成分时，检测到了 PAEs 的存在，定量方法为峰面积归一化法；另外，茶叶包装大都采用塑料包装，尤其是中 低档茶叶，塑料包装物中存在的 PAEs 有可能迁移至茶叶进而污染茶叶。本文综述了 PAEs 在茶叶中存在情况并对其可能的来源进行了 分析探讨。 关键词：邻苯二甲酸酯；茶叶；来源 Occurrence and Sources of Phthalate Esters in Tea YIN Peng, CHEN Hongping, LIU Xin, PAN Rong, ZHANG Minglu （Tea Research Institute, Chinese Academy of Agricultural Sciences, Zhejiang, 31000,China ） Abstract: Phthalate esters (PAEs) are the endocrine disrupting chemicals and can lead to teratogenesis, carcinogenesis and mutagenesis. Moreover, PAEs have estrogen effects, which might cause the endocrine disorder of the male and result in the decline of sperms. On the basis of the side effects of PAEs on human health, PAEs have been listed the priority pollutants by many countries. PAEs were determined in tea when the volatile compounds or aromatic components of tea were studied by the scholars from the home and abroad, but the quantitative methods were peak area nomarlization methods. What’s more, tea, especially low and medium grade tea, is always packaged in plastic bags or containers. The PAEs, existed in the plastic bags or containers, may lose from the polymeric matrix and pollute the tea. This article reviewed the occurrence of PAEs in tea and discussed the possible sources of PAEs in tea. Keywords: Phthalate esters, tea, source 1 邻苯二甲酸酯类化合物简介 邻苯二甲酸酯 (Phthalate esters, PAEs) 的主要用作增塑剂添加到塑料包装和塑料制材等高分子聚合物中以增强 材料的柔韧性和拉伸性，其结构通式见图 1。PAEs 在塑料制品中与塑料的相溶性较好，但与塑料基质并不形成共价 键，而是由氢键或范德华力相连，因此随着时间的推移会迁移至外界环境，进入大气、水体、土壤及生物体中。邻 苯二甲酸二异丁酯（Diisobutyl