通过密度泛函理论计算指导钠掺杂单分散镧系硫氧化物控制合成超薄纳米盘2011年10月(通讯).pdfVIP

Communications DOI: 10.1002/anie.201105025 Doped Nanocrystals Sodium Doping Controlled Synthesis of Monodisperse Lanthanide Oxysulfide Ultrathin Nanoplates Guided by Density Functional Calculations** Yi Ding, Jun Gu, Jun Ke, Ya-Wen Zhang,* and Chun-Hua Yan* Doping of nanocrystals is an intriguing field, since the precursors, this method was limited to only a few lanthanides intentional introduction of impurities has long been regarded (i.e., Sm, Eu, Gd).[4a] as a major way of tailoring the properties of materials. On the basis of both experimental characterization and Furthermore, it was recently found that the use of dopants in DFT calculations, we now demonstrate that introduction of the synthesis of inorganic colloidal nanocrystals can not only monovalent Na+ ions as dopants in trivalent Ln3+ host lattices introduce novel properties but also influence shape and size can significantly facilitate the formation of Ln O S NCs in 2 2 evolution during nanocrystal nucleation and growth.[1] For oleic acid (OA)/oleylamine (OM)/1-octadecene (ODE) example, Liu and co-workers showed that NaYF4-based mixed solvent by creating oxygen vacancies in the host lattice nanocrystals can be precisely tuned in size, phase, and during sulfurization reactions. upconversion emission through Gd3+ doping