燃烧合成钇铝石榴石(YAG)绝热温度计算与实验验证.pdfVIP

Materials Transactions, Vol. 51, No. 12 (2010) pp. 2230 to 2235 #2010 The Japan Institute of Metals Predicting the Adiabatic Temperature of Transparent Y Al O Prepared 3 5 12 via Combustion Synthesis under Ultra-High Gravity 1;2 1;* 1 3 3 Yuepeng Song , Hyoung Soep Kim , Chong Soo Lee , Jiangtao Li and Jun Pei 1Department of Materials Science and Engineering, Pohang University of Science and Technology (POSTECH), Pohang 790-784, Korea 2Mechanical and Electronic Engineering College, Shandong Agricultural University, Tai’an Shandong 271018, China 3 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China In this paper, the adiabatic temperature of a transparent yttrium aluminum garnet (YAG) preparation using a NiO/Al/Y O 2 3 aluminothermic system was calculated based on a thermodynamic theory. The results show that the adiabatic temperature without preheating reaches the 2891 K, which is higher than the melting points of YAG and Ni. The liquid phase mixture products can be separated and densified under ultra-high gravity (UHG). In the preheating temperature range of 620 K2790 K to the reactants of this system, the adiabatic temperature is the same as 3156 K, the boiling point of Ni products. The theoretical analyses and experimental results prove the effectiveness of the YAG fabricated via combustion synthesis under an ultra-high gravity field. [doi:10.2320/matertrans.M2010266] (Received August 6, 2010; Accepted September 30, 2010; Published