变压吸附法富集低体积分数含氧煤层气的研究.pdfVIP

36 1 V o l. 36 N o. 1 20 11 1 JOURNAL OF CH INA COAL SOC IETY J an. 2011 : 0253- 9993( 20 11 01- 009 1- 06 杨 雄, 刘应书, 李永玲, 张传钊, 孟 宇, 杨海军 ( , 100083 : 为了解决低体积分数含氧煤层气无法富集利用的问题, 研究了甲烷体积分数为 20% 的煤 矿抽排瓦 的变压吸附富集过程为了保证富集过程的安全, 吸附过程中使用混合吸附剂, 同时吸 附甲烷和氧气, 使得排放气和解吸气中甲烷和氧气体积分数都处在安全范围内实验研究了吸附 塔高径比吸附时间吸附剂比例节流孔直径反吹时间等对分离效果的影响结果表明: 在碳分 子筛和活性炭作为混合吸附剂的体系中, 其质量之比为 34 时可以将甲烷体积分数安全地提浓到 30% 以上, 此时排放气中甲烷体积分数低于 3% , 氧气体积分数低于 10% : 煤层气; 变压吸附; 甲烷; 氧气; 分离 : TD712; P6 1811 : A Study on low concen tration oxygenbearing coalm ine m ethane en richm en t by pressure sw ing ad sorption YANG X iong, L IU Y ingshu, L I Y ongling, ZHAN G Chuanzhao, MENG Y u, YANG H aijun ( S chool of M echanical Eng ineering, Univers ity of S cience and T echnology B eij ing, B eij ing 100083, Ch ina ) Abs tract: In order to so lve the problem that the low concentration oxygenbearing coa lm ine m ethane can t be concen trated and ut ilized, the pressure sw ing adsorption processes for enr ich ing m ethane from the ex tracted coa l m ine m eth ane w as studied expermi entally, and the coal m ine m ethane s concen trat ion w as 20% . T o ensure the safety o f the en richm ent process, m ixed adsorbentsw as u sed, w hich can adsorb m ethane and oxygen smi u ltaneou sly, so that the oxygen and m ethane concentrat ion of both vent gas and desorption gas of the process w ere in safe range. T he e ffects of adsor ber lengthtod iam e ter rat io, adsorption t mi e, rat io of adsorbents, orifice diam eter, purge tmi e on the processw ere inves t igated. T he resu lts show that tak ing the carbon m o lecular sieve and activated carbon adsorbent as the m ixed adsor bent, the m ethane