湖南大学学报投稿最后.docVIP

溶剂对导电聚吡咯防腐蚀性能的影响 李国希(, 高桂红, 汤小辉, 孙涛, 谢香伦, 曾静 (湖南大学化学化工学院, 长沙 410082)NaClO4的乙腈溶液中或水溶液中在不锈钢表面制备了聚吡咯(PPy)膜. 用扫描电子显微镜观察PPy膜的表面形貌, 用1 mol/L H2SO4溶液中的动电位极化曲线和电化学阻抗谱研究PPy膜对不锈钢的防腐蚀性能. 结果表明, 两种PPy膜都是由球状粒子组成, 但在水溶液中制备的PPy膜结节较多. 有PPy膜保护的不锈钢的自腐蚀电位比不锈钢的显著正移, 自腐蚀电流密度从不锈钢的3580 μA/cm2下降到40 μA/cm2(水溶液)和9 μA/cm2(乙腈溶液). 乙腈中制备的PPy的界面电荷转移电阻总大于水中制备的PPy的界面电荷转移电阻. 在乙腈中制备的PPy膜对不锈钢有较好的抗腐蚀性能. 这是由于溶剂乙腈的亲核性较水小, 与中间聚合体的作用小, 终止链反应较难, 使得PPy聚合链共轭度长、结构缺陷少. 关键词：聚吡咯；不锈钢；防腐蚀；导电高分子 中图分类号：O646 文献标识码：A Effect of Solvents On Anticorrosion of Conducting Polypyrrole LI Guo Xi*, GAO Gui Hong, TANG Xiao Hui, SUN Tao, XIE Xiang Lun, ZENG Jing (College of Chemistry and Chemical Engineering, Hunan Univ, Changsha 410082) Abstract: The Polypyrrole(PPy) film was synthesized in pyrrole and NaClO4 aqueous solutions or acetonitrile solutions on stainless steel by cyclic voltammetry. The surface morphology of PPy was observed by SEM, and its anticorrosion property was investigated by potentiodynamic polarization curves in 1 mol/L H2SO4. As it turned out, it has more Spherical Particles irregular stacking formed lump of breast gland that preparated in aqueous electrolyte. The PPy film shift the corrosion potential of stainless steel visible to positive direction, and decrease the corrosion current density from 3580 μA/cm2 to 40 μA/cm2 and 9 μA/cm2. The impedance of interfacial charge transfer of PPy made in acetonitrile solutions is always greater than the other. The good corrosion resistance of PPy film polymerizated in acetonitrile solutions may be due to the effect of solvents on polymerization process. The Nucleophilicity of acetonitrile is smaller than water that effect little on middle polymer and difficult to end the chain reactions. It is made the conjugacy-lengths and have little structure defect. Keywords: Polypyrrole; stainless steel; anticorrosion;conducting polymers 在电化学制备聚吡咯(PPy)时吡咯先氧化成阳离子自由基再由阳离子自由基发生偶合形成PPy[]. 溶剂的亲核性质对吡咯聚合有很大影响溶剂的亲核性越大溶剂分子与聚合过程中产生的带正电荷的中间产物的作用越强烈导致PPy膜的导电性和力学强度越低[3]吡咯的