电镀锌板无铬耐指纹涂层破坏机制研究.pdfVIP

The 6th China Corrosion Conference Study on the Failure Mechanism of the Chrome-Free and Fingerprint Resistant Coating on Electro-Galvanized Sheet Yanqing WANG, Ning LI, Deyu LI, Zhongli ZOU, Ning XIAO, Zhen ZHENG, Bing LI Institute of Chemical engineering, Harbin Institute of Technology, Harbin, China, 150001 Email: wangyanqingabcd@163.com Abstract: Today anti-fingerprint coating as a kind of organic - inorganic hybrid material is widely used in the surface treatment of galvanized sheet. As thin thickness of organic - inorganic hybrid type of material, its failure mechanism is different from pure thicker organic coating layer or the inorganic coating, has its par- ticularity. The XPS test of coating shows that the surface film is mainly composed of resin and nano-silica, the metal content is more close to the base. Titanium which mainly exists in the form of titanium dioxide, but the XPS detection of trivalent titanium oxide, titanium plays the role of passivation to a certain extent and Zirconium mainly exists in the form of hydrogen phosphate salt. There are also a part of zirconium exists in the form of hydrogen phosphate salt or the carbon compounds, but only four price. And the passivation of zir- conium salt is not found. The corrosion morphology test and Electrochemical impedance spectroscopy (EIS) tests are used to study the corrosion behavior of fingerprint resistant coating in 3.5mass% NaCl solution at different immersion time, and according to bode diagram and simulation circuit model, failure mechanism of fingerprint resistant coating is proposed. Keywords: Electro-galvanized sheet; chrome-free and fingerprint resistant coating; Immersion tes