一种新型含磷液晶阻燃共聚酯.pdfVIP

一种新型的含磷液晶阻燃共聚酯 阮超 杨荣 钟海艺 陈力 王玉忠 四川大学化学学院降解与阻燃高分子材料研究中心、环境友好高分子材料教育部工程研究中心、环保型高分子材料国家地方联合工程 实验室，成都610064 通过采用具有刚性链的芳香族结构二酸或二酯和柔性链结构的二醇以及含磷单体9，10-二氯-9-氧杂 -10磷酰杂菲-对苯二酚二羟乙基醚(DOPO-HQ-HE)，通过无规共聚合成了一种新型含磷液晶共聚酯(PDEBP)。用1H NMR对共聚酯的结构进行了表征，用TGA、DSC和POM对其热性能及液晶行为进行了研究。结果表明，阻燃单体 DOPO-HQ-HE的引入不会降低共聚酯的热稳定性，含7.5mol％DOPO-HQ-HE的共聚酯PDEBP7.5在700℃的氮气氛 中的残余物 （wtRR700）可达31.9wt％，DOPO-HQ-HE含量的增加对共聚酯的结晶性有较大的破坏， 5mol％DOPO-HQ-HE的共聚酯PDEBP5的清亮点温度为154.2℃，焓变为4.64J/g，而PDEBP7.5在POM测试中在升 温及降温过程中均难观察到液晶相的双折射现象。 液晶聚合物；含磷单体；合成；阻燃 ANOVELPHOSPHORUS-CONTAININGFLAME-RETARDANTLIQUID CRYSTALLINECOPOLYESTER RUAN ChaoYANGRongZHONGHai-yiCHEN LiWANGYu-zhong CenterforDegradableandFlame-RetardantPolymericMaterials,CollegeofChemisny,StateKeyLaboratoryofPolymer MaterialsEngineering,NationalEngineeringLaboratoryofEco-FriendlyPolymericMaterials(Sichuan).SichuanUniversity,Chengdu 610064,China novelphosphorus-containingliquidcrystallinecopolyester (PDEBP)wassynthesizedviaa phosphorus-containing diol, 2-(6-oxido-6H-dibenzc,e1,2oxaphosphorin-6-yl) -l,4-phenylenebis(oxy)diethanol(DOPO-HQ-HE)togetherwitharyldiol/dicarboxylateanddiol.Chemical structureofthePDEBPwascharacterizedby1HNMRspectroscopy,andthethermalandliquidcrystalline behavioursofthecopolyesterswereinvestigatedbythermogravimetricanalysis(TGA),differentialscanning calorimetry(DSC)andhot-stagepolarizingopticalmicroscope(POM).TGAresultssuggestedthatchar formationofthecopolyesterswasimprovedwiththeintroductionofDOPO-HQ-HEwithoutdestroyingthe initialthermalstabilityofthepolymer,andtheresidueat700℃ inN2(wtR700)ofPDEBP7.5(7.5mol％ of DOPO-HQ-HEincopolyester)reached31.9wt％,havingapositiveinfluenceofflameretardanceofthe copolyesters.DSCtestssuggestedthatthecrystallinityofthecopolyesterswasdestroyedbyincorporating DOPO-HQ-HEintothemainchainduetothebu