反应气氛对钾系亚熔盐分解钛铁矿的影响机理研究.pdfVIP

反应气氛对钾系亚熔盐分解钛铁矿的影响机理研究 1，2 2 2 2 1 21 李洁 ，王丽娜 ，初景龙 ，曲景奎 ，孙体昌 ，齐涛 (1北京科技大学土木与环境工程学院，北京 100083，2 中国科学院过程工程研究所绿色过程与工程重点试 验室，北京 100190) 摘要：详细探讨了反应气氛对钾系亚熔盐分解钛铁矿制备钛酸盐晶须过程的影响，研究了氧化/非氧化条件 对钛的转化率、产物的形态与组成、产物中铁的形态变化和反应动力学的影响。实验结果表明，在反应前 期，耗氧量较大，氧气的存在加速了反应的进行，使钛的转化率较空气和氮气条件下有所提高，但反应气 氛对钛的最终转化率影响不明显；XRD 数据表明，三种反应气氛条件下得到的产物均为结晶良好的三钛酸 钾（K Ti O ）；SEM 结果表明，三种条件下得到的产物形态均为晶须状，而氮气气氛下得到的晶须结块现象 4 3 8 少，生长情况较好；氧的存在加快了反应过程中铁的转化，使其在反应初期阶段很快将铁由二价氧化为三 价，破坏了钛铁矿的晶格，促进了钛的转化。 关键词：钛铁矿；亚熔盐；氧化；非氧化 The study of atmosphere effect on decomposition of ilmenite by potassium sub-molten salt 1,2 2 2 2 1 2 Li Jie , Wang Lina , Chu Jinglong , Qu Jingkui , Sun Tichang , Qi Tao (1.School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing, 100083，China; 2. Key Laboratory of Green Process and Engineering，Institute of Process Engineering ，Chinese Academy of Sciences, Beijing, 100190 ，China) Abstract: The effect of reaction atmosphere on decomposition of ilmenite by potassium sub-molten salt was studied. The effects of the reaction atmosphere (oxidation/non-oxidation) on Ti conversion, the crystal phase, the morphology of product as well as the ferrum contents were investigated in detail. The results showed that different atmospheric conditions influenced the ilmenite decomposition rate, especially in the early stage of the reaction. It was shown that the existence of oxygen accelerated the reaction, and Ti conversion was higher than that in non-oxygen atmosphere. XRD data indicated that the potassium titanate whiskers (K Ti O ) in the