聚合物锂离子电池特性的试验.pdfVIP

ISSN1674—8484 汽车安全与节能学报，2011年，第2卷 第 1期 07／13 — C—N—ll—5—90—4／U— JAutomotiveSafetyandEnergy 53—57 - 2011．Vo1．2 No．1 , TestsonElectricalCharacteristicsofPolymerLithium--ion Batteries ZHANG Yanqin，HU Bo，FENG Nenglian，ZHOU Dasen CollegeofEnvironmentalandEnergyEngineering，BeOingUniversityofTechnology BeOing100124，China Abstract：Theelectricalcharacteristicswereanalyzedusingthreeexperimentalmethodswithacommerciaf20-Ahpolymer lithium．iOnbattery．ThefirsImethodlSaconventionallest，inwhichlhevoltagesaremeasuredaslhesteadyopen。circuit voltagesafter12-hreslaldifferenlstateOfcharge．Thesecondislherapid eslformeasuremenlOfopencircuilvoltagesduring lhechargeanddischargepulsewith1-minrest，withlhelhirdbeingtheconstant—currenlpulseles1with30。mlnreslforparameter identificationbasedonlheequivalentcircuilmodelThemeasuremenlresultsshowlha¨heconstant-currenlpulsemethodwith 30．minutesrelaxationiSeffectivelOderivebothlheopen—circuitvoltage OCV curveandlheelectricalparameters． Keywords：polymerlithium-ionbatteries；electricalcharacteristics；tests；model；parameters 聚合物锂离子电池特性的试验 张彦琴，胡 博，冯能莲，周大森 北京工业大学 环境与能源工程学院，北京 100124 摘 要：为研究聚合物锂离子电池特性，用三种试验方法，对一种标称容量为 20Ah的商用锂离子电池，试验研究 电池特性。第一种为常规方法，将不同荷电状态电池静置 l2h后测量其开路电压；第二种方法为快速测试方法，每 种荷电状态电池静置 1min后测量其端 电压；第三种方法是测量不同荷电状态电池静置 30min后的端电压，用测 量数据外推开路电压和电池模型参数。测试结果表明：采用30min休息间隔的脉冲充放电可有效用于测试电池的开 路电压 OCV 曲线和电池电特性参数。 关键词 ：聚合物锂离子电池；电特性；试验；模型；参数 中图分类号：TM912．1 IntrOductiOn Forthesereasonspolymer1ithium ·ionbatteriesfindtheir applicationsbothinportableelectronicdevices，electric Themainadvantageofpolymer1ithium—ionbatteriesiStheir andhybridvehicles[3-4】 improvedsafetyunderovercharge_l』_Buttherearemore ． Itisessentialtounderstandindepth thecell’Selectricalcharacteristicsfordesigningabattery advantagesthanjustthelackofexplosions．Insteadofstoring thelithium—ionsinliquidsolvents．the1ithium—ionsareheldin managementsystem BMS ，whichisrequiredtofulfillthe solidstatepolymer gelled matrix，SOthereislesschancefor functionssuchascellprotection，stateofchargeandstateof h