G3镍基合金中相的溶解及其析出特性的研究.pdfVIP

2011 年特钢年会论文集 2011 年 9 月 G3 镍基合金中相的溶解及其析出特性研究 1 1 1 1 2 张同波 ，李京社 杨树峰 ，唐海燕 ，包耀宗 (1.北京科技大学冶金与生态工程学院, 北京 100083，2.钢铁研究总院结构材料研究所，北京， 100081) 摘要：本文通过计算对 G3 合金在热力学平衡条件下可能存在的析出相及各析出相中的化学 成分进行分析推测，并采用 SEM、TEM 分析进一步验证了敏化处理后第二相的分布状态、衍变 的基本规律，结果表明：物理化学相分析结果与热力学相计算结果基本吻合。在 500°C 以上， G3 合金中稳定存在的平衡相有 ζ、M23C6 、M6C 相。500°C～821°C 为 ζ、M23C6 两相共存， 到 821°C 又有 M6C 相析出，随着温度升高，M23C6、ζ 先后消失，到 1093°C 时所有析出相溶 解。 关键词：G3 镍基合金，溶解，析出，热力学 Study on characteristics of phase dissolution and precipitation of G3 Alloy 1 1 1 1 2 Yu Man ,Li Jingshe , Yang Shufeng ,Tang Haiyan , Bao Yaozong （1.Metallurgical and Ecological Engineering School，University of Science and Technology Beijing ，Beijing 100083 ，China 2. Institute of Structural Materials,Central Iron and Steel Research Institute, Beijing 100081 ） Abstract In the present paper ,the possible precipitates and their chemical constituents in G3 alloy have been predicted by calculation under thermodynamic equilibrium conditions. At the same time, SEM and TEM are used in order to further demonstrate both the distribution and the evolution of the secondary precipitates after sensitized treatment. The results show that the physico-chemical phase analysis basically matches the thermodynamic phase calculation. When it is higher than 500℃, the stable existing equilibrium phases are σ , M23C6 and M6C. When the temperature is between 500 ℃ and 821 ℃, σ -M23C6 biphase coexistents. When it reaches 821℃, M6C appears. Later, wit