端羟基聚醚酯多元醇研制.pdfVIP

端羟基聚醚酯多元醇的研制 5 上海塑料6 2011 年第4 期( 总第156 期) # # 董 旭, 顾 尧 ( , 266042) 利用DM C 催化PO, 邻苯二甲酸酐( PhA) 与CO2 三元共聚合成端羟基聚醚酯多元醇, 并研究 PhA 对聚合反应的影响 规律实验发现: PhA 的引入可提高催化剂的催化活性, 缩短反应时间; 适量的PhA 可减少副产物环碳酸酯的生成; 另外, PhA 的引入会使聚合产物的黏度明显增加, 使得浇注聚氨酯材料时可操作性变差; 聚合产物的相对分子质量分布较PO 与CO2 共聚 物的变窄; 合成较高相对分子质量的聚醚酯多元醇时(M n 4 000) , PhA 的质量不要超过PO 质量的 15% 聚醚酯多元醇; 三元共聚; DM C 催化剂 :T Q 3201 66+ 3 :A : 1009-5993( 2011) 04-0016-04 Stud on Novel Pol etherest er Pol ol DONG Xu , GU Yao ( Ke Laborator of Rubber-Plast ics, Ministr of Education, Qingdao U niversit of Science and T echnolog , Qingdao 264002, China) Abstract:H drox -l term inated pol etherester pol ols w ere s nthesized b copol mer ization of PO, PhA and CO2 catal zed b DMC catal st . The effects of PhA on the pol merization w ere studied. It w as found that the introduction of PhA can impr ove the catal tic activit of the catal st and shorten the pol - merization time. The c clic carbonate could be reduced while adding in appropriate amount of PhA . In addition, it increased the v iscosit of products obv iousl and then caused the operabilit of pol urethane PhA materials poor. T he relative molecular mass distribution w as narrow er com par ed with PO-CO2 co- pol m er, but still relativ el w ide. The mass ratio of PhA and PO w as m ostl no more than 15% w hen s nthesizing high r elative molecular mass pol ether ester pol ols, and can be increased w ith the relatine molecular mass decreased. Key words:pol etherester pol ol; ternar pol mer ization; DM C catal st [1] Pxominska 0 PU , PU , ; , , , PU PU