改性花生壳对水中铬铅的吸附作用.pdfVIP

农业环境科学学报 2011,30(7):1404-1408 Journal of Agro-Environment Science 改性花生壳对水中Cd2+和Pb2+ 的吸附研究 1 1，2* 1，2 1 林芳芳 ，易筱筠 ，党 志 ，郑刘春 （1.华南理工大学环境科学与工程学院，广州 510006 ；2.工业聚集区污染控制与生态修复教育部重点实验室，广州 510006） 摘 要：用高锰酸钾对花生壳进行改性，制成改性花生壳吸附材料，并进一步就该吸附剂对水中重金属离子Pb2+ 、Cd2+ 的吸附去除性 能进行了考察，结果表明，吸附在18 h 后基本达到平衡，吸附Pb2+和Cd2+最佳初始pH 值分别为4.5 和6.5 ，对Pb2+ 的吸附量最大达 到104.75 mg·g-1 ，对Cd2+ 的吸附量最大达到43.11 mg ·g-1 。对Pb2+和Cd2+在该吸附剂上的竞争吸附研究结果表明，竞争吸附的干扰使 得Cd2+ 的吸附量降低88.47%，Pb2+ 的吸附量降低20.80% ，且Pb2+ 的吸附量为Cd2+ 的5~6 倍，吸附剂对重金属离子的吸附选择顺序为 Pb2+＞Cd2+ 。 关键词：改性；花生壳；镉；铅；吸附；竞争吸附 中图分类号：X703.1 文献标志码：A 文章编号：1672- 2043(2011)07- 1404- 05 Adsorption of Cd2+ and Pb2+ from Aqueous Solution by Modified Peanut Shells 1 1,2 1,2 1 LIN Fang-fang , YI Xiao-yun , DANG Zhi , ZHENG Liu-chun （1.College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, China; 2. The Key Lab of Pollution Control and Ecosystem Restoration in Industry Clusters, Ministry of Education, Guangzhou 510006, China） Abstract ：The objective of this study is to seek for a low cost adsorbent material to remove heavy metal ions from aqueous solution. As a high volume agricultural waste, peanut shells were modified with KMnO4 to produce biomass adsorbent. The adsorption capacity of the modified ad－ sorbents to remove cadmium （Ⅱ）and plumbum （Ⅱ）from aqueous solution were investigated in different conditions. Results showed that the optimum initial solution pH values for adsorption were 4.5 for the lead and 6.5 for cadmium, respectively. The adsorption could reach equilib－ rium in about 18 hours. The maximum adsorption capacity was 104.75 mg ·g-1 for Pb2+ and 43.11 mg ·g-1 for Cd2+ . In addition, the competitive adsorption of Pb2+ and Cd2+ on the modified peanut shells was investigated and the results showed the adsorption capacity of Pb2+ or Cd2+ was markedly restrained wit