萃取法去除油页岩干馏污水中酚类物质的研究_关晓辉.pdfVIP

第 25卷 第 15期 中国给 水排 水 Vo.l 25 o. 15 2009年 8月 CHI A WATER WASTEWATER Aug. 2009 关晓辉, 于海斌, 宋广亮 (东北电力大学 化学工程学院, 吉林省 吉林市 132012) : 采用乙酸 丁酯萃取 页岩干馏污水中的酚类物质, 考察了 pH 水比温度搅拌强 度搅拌时间萃取剂的重复使用次数对除酚效果的影响试验结果表明, 采用乙酸 丁酯对 页岩 干馏污水进行处理是可行的, 其最佳处理条件为: pH 值为 6. 50 水比为 15温度为 30~ 40 搅拌强度为 200~ 300 r/m in搅拌时间为 10~ 20m in,在此条件下平均除酚率可达 90%以上用乙 酸 丁酯萃取 页岩干馏污水, 不但萃取时间短除酚效率高,还为后续生化处理创造了条件 : 页岩干馏污水; 萃取; 除酚 : X703 : C : 1000- 4602(2009) 15- 0086- 03 R em oval of Phenols from O il Shale R etortW astew ater by ExtractionM ethod GUA Xiao-hui, YU Ha-ibin, SO G Guang-liang (S chool of Chem ical Eng ineering, N ortheast D ianli Un iversity, J ilin 132012, Ch ina ) Abstract: Thebutyl acetatewas used to extract the phenols from oil shale retortwastewater. The influence ofpH, ratio of extractant towastewater, temperature, stirring intensity, stirring tmi e and repet-i tion tmi es of extractant on phenol removal efficiencywas investigated. The results show that treating the oil shale retortwastewaterby butyl acetate is feasible. The optmi um conditions are as follow s: thepH va-l ue is 6. 50, the ratio of extractant towastewater is 15, the temperature is 30 to 40 , the stirring intensity is 200 to 300 r/m in, and the stirring tmi e is 10 to 20 m in. Under the above conditions, the av- erage removal rate of phenols is above 90% . Treating the oil shale retortwastewater by butylacetate has short extraction tmi e, high removal rate of phenols, and creates the conditions for the subsequent bio- chem ical treatm ent of thewastewater. K ey w ords: oil shale retortwastewater; extraction; phenol removal , , [ 2] ,