肉桂酸丙酯合成方法的改进.pdfVIP

维普资讯 第 18卷第 3期 青 岛 大 学 学 报 Vd．18No．3 2003年 9月 JOURNALOFQINGDAOUNIVERSITY Sep．2003 ArticleID：1006—9798(2003)03—0042—04 CATALYTIC SYNTHESISOF N．PROPYL CINNAM ATE W ITH TiSiW 12040／TiO2 YANGShui—jin ．XU Lou-jin (DepartmentofChemistryandEnvironmentalEngineering， HubeiNormalUniversity，Hunagshi435002，China) Abstract：ThecatalyticactivitiesofTiSiWl2o40／]ri02insynthesizing n—propylcirmamatearere— ported．Itisdemonstratde thatTiSiWl2O40／Ti02isna excellentactalyst．Variousfactors∞n— cemedinthisreactionareinvestigatde ．Theoptimum conditionsisfound，thatis，themolarra— tioofalcoholtoacidis9：1，themassratioofthecatalystusedtothereactnats2．0％ ，thereac- tiontemperature90—100℃ ，nadthereactiontime3．0h．Underthiscondition，theyieldof n- propylcinnamateis62．0 ％． Keywords：n-propylcirmamate；TiSiWl2O40／]ri02；catalyst CLCnumber：TQ426．91；TQ655 Docmu entcode：A Then—propy1cinnamateisaveryimportnatperfumematerialE·2。 ． Uptonow ，therearemanymethodsto sny thesizethem．ConventionallyHESO4isusedascatalystinfactories，butitcausesmanyproblems，suchasthe erosionofequipment，difficultyforafter-treatment，low qualityoftheproducts，etc．Theactalyticfunctionofhet— eropolycompoundsoftung stennadmolybdenum hasrecentlyattractedmuchattentionofrvariousindustrialpro— cesseS，suchaSoxidation，hydration，esterifiaction[。～6。etc，particulralyinthelasttwodecades，becausetheir ， acidicnad rdeox properties can be controlled at atomic／molceulra levels．M izuno， Kozhevnikov[1]nadW nagEnbo[12,13]havereviewde t