溶剂热法制备六角锥形ZnO及其光致发光性能.pdfVIP

理化学学报(Wuli Huaxue Xuebao) March Acta Phys. Chim. Sin., 2008, 24(3) ：539-542 539 [Note] 溶剂热法制备六角锥形ZnO 及其光致发光性能 冬 张树朝 (中国铝业股份有限公司郑州研究院, 郑州 450041) 摘要： 通过乙酸锌和醇溶液反应得到了六角锥形纳米ZnO 颗粒, 反应过程中不使用碱溶液和表面活性剂. 利 用透射电子显微镜(TEM) 、选区电子衍射(SAED)及扫描电子显微镜(SEM)对其形貌和结构进行了表征分析. 结果 表明, 此方法制备的ZnO 颗粒为单晶, 而且六角锥形ZnO 的室温光致发光谱(PL)在378 nm 处显示出了单纯的 紫外发射峰, 而不是通常报道的可见光区发射, 这也预示着这种特殊结构的纳米ZnO 将会成为一种具有良好应 用前景的光学材料. 关键词： 氧化锌; 六角锥形; 光致发光性能 中图分类号： O648; O614.24 Synthesis of Hexagonal Cone Shaped ZnO Nanoparticles Using Solvothermal Reaction and Its Photoluminescence Property HAN Dong ZHANG Shu Chao (Zhengzhou Research Institute, A luminum Corp oration of China Limited, Zhengzhou 450041, P, R. China) Abstract ： Hexagonal cone shaped ZnO nanoparticles were synthesized by the esterification between zinc acetate and alcohol with non basic solution route. For the formation process of ZnO nanoparticles, no bases, surfactants, or catalysts were used. Transmission electron microscopy (TEM), selected area electron diffraction (SAED), and scanning electron microscopy (SEM) measurements were used to investigate the morphology and structure. The synthesized ZnO nanoparticles were singlecrystal with hexagonal phase. Furthermore, the as prepared ZnO particles showed a strong UV emission at 378 nm due to the annihilation of excitons, indicating that the ZnO nanostructure was promising as a high performance optical material. Key Words ： ZnO nanoparticle; Hexa