PVC_ABS和PVC_CPE两种共混体系的结构和性能.pdfVIP

24 1 Vol.24, No. 1 2003 2 Journal of Qiangdao University of Science and T echnology eb. 2003 : 1001- 4764(2003) 01- 0048- 05 PVC ABS/ PVC CPE/ , , , , ( , 266042) ; 研究了PVC ABS/ 和PVC CPE/ 两种共混体系的结构形态与力学性能的关系, 用电子显微镜( SEM 、T EM) 观察冲 断面、拉伸断面形貌。结果表明, 随改性剂用量不同, 两种共混体系冲 性能曲线均呈现 “S”型, 不同的是, ABS 是以颗粒或聚集体分散在PVC 连续相中, CPE 在 PVC 中形成网络结构; 拉伸时, ABS 作为应力集中体引发银纹, CPE 易与基体共同发生剪切屈服, 产生 “剪切带”, “银纹”和 “剪切带”都对PVC 增韧起着重要 作用。 : ABS; CPE; 改性; 结构与性能 : O 631. 1　　　: A Microstructures and Properties of PVC/ CPE and PVC/ ABS Blends ZHOU Li-ling, WANG in, LIN Yu-sheng, YANGJing-yi, WU Qi-ye ( Colleg e of Polymer Science and Engineering, Qingdao U niversity of Science and T echnology, Qing dao 266042,China) Abstract In this paper the influences of CPE and ABS on the mechanical properties of: , PVC/ CPE and PVC/ ABS blends were studied . T he experimental results showed that the impact strength of the blends depended on the dosage of ABS and CPE. T he mi- crostructure and fracture surface of the blends were also investigated by SEM and T EM . It was found that ABS was dispersed in the form of particles or aggregates in PVC matrix while CPE tended to be dispersed as a network structure. In the tensile testing, “ ” the ABS acted as a stress center to toughen the PVC matrix and the craze was formed - and the CPE with the PVC matrix together gave a yield deform by shear stress to form theshear belt.T he formations of craze and shear belt had different contributions to the toughening of PVC. Key words ABS CPE: ; ; ameliorate structure and capability; [ 13]