SnCl2,SnCl4为前驱体的柠檬酸凝胶法制备的20%RuO2-80%SnO2组织研究.pdfVIP

228 材料工程／2008年lo鹚 SnCl2，SnCl4为前驱体的柠檬酸凝胶法制备的 20％Ru02—80％Sn02组织研究 onMicrostructureofz0％Ru02一a0％Sn02 Study Preparedby Method and asPrecursor SnCl2SnCl4 Citrate～gel Using 鄂掩群，唐电 (福州大学材料研究所，福州350108) SHAO Dian Yah—qun，TANG (InstituteforMaterials Research，Fuzhou 350108，China) University，Fuzhou XRD、TEM和比表面(BET)等测试技术研究了产物的组织结构。结果表明：粉体为分散性岚好、尺寸分布均匀、具有优 Sn02翔RuOz混合物。钌出现鹃激发眈单一黻RuCl3为源物震程孪出现静温度离，超过钛霞穰的常规涮备潺度450 热的比袭面积大，前驱体为SnCI：制备的粉末的比波面积具有比前驱体为SnCI．时的大。 关键键：柠檬酸盐凝黢法f纳寒耪辩；缝织绩梅；Sn饶；Ru02 中圈分类号：TFl23．1，TGl46。13文献标识码：A 文章缡弩：1001-4381(2008)10-0228-04 Abstract：Nano-sized20％Ru02～80％Sn02materialswere the method synthesizedby citrate-gelusing andcitricacidas and ethanolassolvent．Thestructuresof RuCl3，SnCl2，SnCl4 precursoranhydrous thederived werecharacterized andBET isshownthatthemate— powders byXRD，TEM techniques．It rialsobtainedwere of oxide with narrowdistributioninsizeand composedrutile-typephasesfairly thermal ofabout10nmwas resistant sizes obtainedwhen was good properties．(Ru，Sn)02with SnCl2 usedassource mixedoxidesof and wasobtainedwhile was material。Ruffle-typeSn02 RuOz SnCIl usedassourcematerial．Snionscan increasethe thatmetalRUwasformed．It