以硫化钙为还原剂还原-酸浸提取 低品位氧化锰矿中的锰元素.pdfVIP

Trans. Nonferrous Met. Soc. China 25(2015) 1677−1684 Manganese extraction by reduction−acid leaching from low-grade manganese oxide ores using CaS as reductant Chang-xin LI, Hong ZHONG, Shuai WANG, Jian-rong XUE, Fang-fang WU, Zhen-yu ZHANG School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China Received 6 June 2014; accepted 25 September 2014 Abstract: The extraction of manganese from low-grade manganese oxide ores using CaS derived from CaSO4 as reductant was investigated. The effects of mass ratio of CaS to ore, reduction temperature, reduction time, liquid to solid ratio (L/S ratio), stirring speed, leaching temperature, leaching time and H SO concentration on the leaching rates of Mn and Fe during the reduction–acid 2 4 leaching process were discussed. The leaching rates of 96.47% for Mn and 19.24% for Fe were obtained under the optimized conditions of mass ratio of CaS to manganese oxide ore 1:6.7, L/S ratio 5:1, stirring speed 300 r/min, reduction temperature of 95 °C for 2.0 h in the reduction process and leaching stirring speed of 200 r/min, H SO concentration of 1.5 mol/L, leaching temperature 2 4 of 80 °C for 5 min in the leaching process. In addition, this process can be employed in the recovery of manganese from various manganese oxide ores, and Mn leaching rate above 95% is obtained. Key words: manganese; manganese oxide ore; calcium sulfide; reduction; leaching leaching include coal, graphite or sulfur [6,7], pyrite [8], 1 Introduction