低温吸附制备Au-TiO_2复合薄膜及其光电化学性质.pdfVIP

第25卷第11期 无 学 学 报 V01．25 机 化 No．11 2009年11月 CHEMISTRY CHINESEJOURNALOFINORGANIC 2026～2030 低温吸附制备Au．Ti02复合薄膜及其光电化学性质 傅平丰 张彭义★ 环境模拟与污染控制国家重点联合实验室，清华大学环境科学与工程系，北京 100084 摘要：在低温条件下将预先合成的Au溶胶吸附到TiO：薄膜上以制备纳米Au．TiO：复合薄膜。以超高分辨率场发射扫描电镜 Ti0：电极的光生电流提高近5倍，光生电压明显向负值增大，说明纳米Au可增强光生载流子的分离效率，促进电荷在电极与 的复合，提高了电极中载流子浓度。 关键词：低温吸附；Au-TiO：复合薄膜；光电化学性质；交流阻抗谱 中图分类号：0614．123；0614．41+1文献标识码：A 文章编号：1001-4861 2009 11-2026-05 Photoelectrochemicalof Film Au-Ti02 Properties NanocompositePrepared Method byLow-temperatureAdsorption FU ZHANG Ping-Feng Peng-Yi+ State Joint SimulationandPollution Key LaboratoryofEnvironment Control,DepartmentofEnvironmental Scienceand Engineering,TsinghuaUniversity,Beoing100084 filmswere Aucolloidson filmsatlow Abstract：Au·TiO：nanoeompositepreparedbyadsorbingprefabricated Ti02 filmswerecharacterizedwith resolution and their Au—Ti02 FESEM，XRDXPS，and temperature．The ultra—high weremeasuredunderUVillumination．Auwithan diameterof photoelectrochemical average properties nanoparticles were onthe filmswith 4．3±1．2 nmhomogeneouslydispersedTi02 hJighloading．ne measurementsshowedthatthe of electrodeWas about5 the TiO卵i folds，and photocurrent improved photovoltage increasedtomore valuesafter Au indicatesthatAu significantly negative depositingnanoparticles．It nanoparticles havethebeneficialrolein the and the photoinducedchargeseparation improving efficiencypromotingcharge transferattheinterfacebetweentheelectrodeand electrochemical fEISl electrolyte．The impendencespectroscopy revealedthattheresistanceof electrodewasreducedtohalfofthatof Au—TiO／ri analyses chargetransfer Rd of thatthecarrier inthe electrodeisincreased therecombination TiOyTi，indicatingdensityAu—TiOYTi bysuppressing of hole—electron photogeneratedpairs． Keywords：low-temperatureadsorption；Au-Ti02nanoeompositefilm；photoelectrochemicalproperties；electrochemicalimpendence spectroscopy TiO：薄膜上沉积纳米Au，可促进界面电荷转制备Au．TiO：薄膜的方法较多，如磁控溅射法[31、光 移，抑制光生载流子复合，提高光催化效率112．1。目前， 还原沉积[41、沉淀一沉积法1