喷雾干燥-氢还原制备超细纳米晶W-10Cu粉末及其烧结行为.pdfVIP

第 15 卷第 4 期 粉末冶金材料科学与工程 2010 年 8 月 Vol.15 No.4 Materials Science and Engineering of Powder Metallurgy Aug. 2010 喷雾干燥−氢还原制备超细/纳米晶 W-10Cu 粉末 及其烧结行为 朱 松，范景莲，刘 涛，田家敏 ( 中南大学 粉末冶金国家重点实验室，长沙，410083) 摘 要：采用喷雾干燥−氢还原法制备超细/纳米晶 W-10Cu(质量分数，%)复合粉末，并经过压制和烧结制备 W-Cu 复合材料，系统研究烧结温度和保温时间对该材料性能和组织的影响，以及在 1 100~1 300 ℃温度范围内的烧结 激活能。结果表明，W-10Cu 还原粉末晶粒度仅为 30~60 nm；在 1 200 ℃烧结时开始发生明显的致密化行为；随 烧结温度升高相对密度增大，当烧结温度升高到 1 300 ℃时W-10Cu 复合材料的相对密度为 90%，但当温度达到 1 460 ℃时有所降低。1 420 ℃保温 90 min 时材料相对密度高达 99.1%，且此时晶粒度仅为 1.8 μm 。W 晶粒尺寸 为 30~60 nm 的W-10Cu 复合粉末在 1 100~1 300 ℃烧结的平均激活能为 129.14 kJ/mol。烧结温度为 1 420 ℃时 W-10Cu 的电导率随保温时间延长先增大后减小，保温90 min 时最大达到 19 MS/m，超过国标有关规定。 关键词：W-10Cu 复合粉末; 超细/纳米晶; 烧结致密化; 激活能; 晶粒长大 中图分类号：TG149.4+ 11 文献标识码：A 文章编号：1673-0224(2010)4-373-05 Preparation and sintering behavior of ultrafine/nanocrystalline W-10Cu composite powders ZHU Song, FAN Jing-lian, LIU Tao, TIAN Jia-min (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Ultrafine/Nanocrystalline W-10Cu (mass fraction, %) composite powders were synthesized by sol-spray drying and subsequent hydrogen reduction process. The W-Cu composite materials were fabricated through pressing and sintering. Effects of sintering temperature and holding time on material properties and microstructure were systematically studied. The sintering activation energy between 1 100 and 1 300 ℃ was also explored in the present paper. The results show that the grain size of W-10Cu powder i