制备条件对NiOSDC阳极基体上LSGMC膜性能影响.pdfVIP

研 究 与 设 计 制备条件对 NiO/SDC 阳极基体上 LSGMC 膜性能的影响 韩艳红 贺天民 , (吉林大学物理学院 吉林长春 130023) ! 摘要： 以未完全晶化的 La0.8Sr0.2Ga0.8Mg0.115Co0.085O3- ! (LSGMC)为原料，用胶体沉积法在 NiO/SDC 阳极基体上制备出 LSGMC 膜。 用 X 射线衍射方法(XRD)、宜流四端法和扫描电子显微镜（SEM ）研究制备条件对LSGMC 膜相成分、电 学性能和表面形貌的影响。研究结果表明，阳极基体锻烧温度对 LSGMC 膜的电学性能具有强烈的影响。 LSGMC 膜经 1 400 C烧结 10 h 具有较高的电学性能和致密性。 1 400 C烧结 10 h 的 LSGMC 膜 800 C 时的电导率达到 0.97 S/cm。 研究还表明，由于 LSGMC 膜在制备过程中，阳极基体中的 Ni 扩散到 LSGMC 膜中，引入了电子电导，因此导致 NiO/SDC 阳极基体上 LSGMC 膜的电导率明显增犬。 关键词：掺杂锭酸铜；固体电解质膜；电学性能 中图分类号：TM 911.4 文献标识码：A 文章编号：1002- 087 X(2006)10- 0813-03 Effect of preparation conditions on properties of La0.8Sr0.2Ga0.8Mg0.115Co0.085O3-! films on NiO/SDC anode substrate HAN Yan-hong, HE Tian-min (College of Physics, Jilin University, Changchun Jilin 130023,China) Abstract ：The incompletely crystallized La0.8Sr0.2Ga0.8Mg0.115Co0.085O3- (LSGMC) powders were used as starting materi- als, the LSGMC films were prepared on NiO/SDC anode support using colloidal deposition method. X- ray diffrac- tion, DC four- probe method and scanning electron microscopy were employed to investigate the effect of prepara- tion conditions on the phase compositions, electrical properties and surface morphology of LSGMC films. The results show that the calcining temperature of the anode substrate strongly affects the electrical properties of LSGMC films. The LSGMC film sintered at 1 400 C for 10 h presents a higher electrical property and densification, and the con- ductivity of