菲并咪唑衍生物的化学结构与其热学性质的关系.pdfVIP

Material Sciences 材料科学, 2013, 3, 168-171 doi:10.12677/ms.2013.34031 Published Online July 2013 (/journal/ms.html) Relationship between Thermal Properties and Their Chemical Structure in Phenanthroimidazole-Based Material Jixin Li, Xiaohui Song, Zhiming Wang School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang Email: wangzhm1983@163.com th th st Received: Jun. 4 , 2013; revised: Jun. 8 , 2013; accepted: Jun. 21 , 2013 Copyright © 2013 Jixin Li et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unre- stricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Abstract: Phenanthroimidazole and its derivatives have attracted more and more attention in preparing bipolar and high-efficiency saturated blue emitters due to their excellent thermal properties. To discuss the effect on the glass transi- tion temperature and thermal decomposition temperature originating from the chemical structure change in phenan- throimidazole-based material, such as the linked position and different substituent groups, 1,2-diphenyl-phenan- thro[9,10-d]-imidazole is chosen as a model compound based on the current results. By tuning the substituent structure and linked mode in the imidazole ring 1,2-position, some regularities are revealed. The analysis results show that the Tg decreases with the increase of the molecular steric and rises with the increases of conjugated degree and planarity, si- multaneously, 2-position of imidazole ring plays a more important role in all substituent positions. The Td is enhanced with the increase of molecular weight,