Mg^2＋、Al^3＋离子增强SrTiO3∶Pr^3＋荧光体发光性能的研究.pdfVIP

第 38卷第 1O期 光 子 学 报 VoL38No．10 2009年 1O月 ACTA PHOTONICA SINICA October2009 EnhancedLuminescenceforSrTiO3：Pr。+ Phosphors with theAddition ofM g+andAI。+Ions ZHANGJian—bin ，DENG Zhou—hu ，YUN Jiang—ni。 (1SchoolofElectricityandInforrnationEngineering，JiangsuTeachersUniversityofTechnology， Changzhou，Jiangsu213001，China) (2SchoolofInformationScienceandTechnology，NorthwestUniversity，Xian710127，China) Abstract：A1。 andM g 一dopedSrTiO3：Pr。。‘phosphorsaresynthesizedbyanew sol—gelmethod andthemechanism ontheenhancementofredluminescenceintensity ofSrTiO3：Pr。 byA1。 andM g additionsareinvestigated．From thephotoluminescence(PI)spectra，X—raydiffraction patternsand Mulliken population analysis，itis speculated’thatone oftheoriginsofthe enhancementistheintensifiedPr—O andTi—O bondsbyadditionofA1。 andMg inSrTiO3： PrH ．BecausethePr—O andTi—O bondsareintensifiedandthecorrespondingbond lengthsare reducedby addition ofA 【。 and Mg。。。in SrTiO ：Pr。 ，thehostto activatorenergy transfer efficiencyisimproved．1eading totheenhancementofluminescenceefficiency ofSrTiO3：Pr抖 ． Andthefundamentalexcitedmechanism inSrTiO3：Pr。。isnotchangedbyadditionofA1抖 and M g外 ． Keywords：SrTiO3：Pr” ；Sol—gelmethod；Firstprinciplescalculation；Co—doping；Luminescence efficiency CLCN ：TG422 DocumentCode：A ArticleID ：1004—4213(2009)10—2624—5 0 Introduction dopedSrTiO3 ：Pr” by a new sol—gelmethod， which hasmany virtues，such as low calcination In 1996， SrTiO ： Pr。。。 was successfully temperature，homogeneousand highproductivity． developed by A1 addition as a potential red Itisob