Bi掺杂对Ca3-xBixCo4O9氧化物微观结构和热电性能的影响.pdf

第39卷第2期 人 工 晶 体 学 报 v01．39No．2 2010年4月 JOURNALOFSYNTHETICCRYSTALS April，2010 Effectof Bi ontheMicrostructureand Doping Thermoelectricof Oxides PropertiesCa3嘎BizC0409 ZHAO Ta02 Li—minl，ZHU ofMathematical and Sciences，HenanInstituteof 451191，China； (1．Department Physical En#neefing，Zhengzhou of and Electronic Normal 2．DepartmentPhysics Engineering，ZhoukouUniversity，Zhoukou466001，China) 16Mawh March (Receitw．d 2009，Ⅲ州232009) were conventionalsolid-statereaction Abstract：Ca3。Bi。C0409(0．0≤x≤0．45)samplespreparedby methodandtheeffectofBi onthemicrostructureandthermoelectricwas doping propertiesinvestigated． XRDand couldbeformedinthe SEM revealedthatc—axis—orientedstructure investigations Bi—containing and0．45 had oforientationand size．whichresultedin samples．石=0．3 sampleslargerdegree grain inthese thesubstitutionofBi3+forCa2+decreasedthehole largerconductivitysamples．Since coefficientsofthe increasedwiththeincreaseofBicontent．The concentration，Seebeck samples power factorof算=0．3 couldreach2．77×10。4W／m·K2at1000K．whichwas tothatof sample