生物质与煤溷燃过程中的腐蚀及其防治措施_岳茂振.pdfVIP

岳茂振, 王永征, 卞素芳, 田素乐, 陆 晨 山东大学能源与动力工程学院, 山东 济南 250061 [ ] 生物质中K 和 Cl 的含量较高, 在燃烧过程中可引起过 器受 面的严重腐蚀, 限制了 其在电厂中的大规模利用生物质与煤混燃技术对上述问题有所改善, 当生物质掺混 比例较低时, 其腐蚀机理与煤燃烧时相似, 腐蚀主要是由氧化和硫化作用引起; 当生物 质掺混比例较高时, 腐蚀主要由KCl 引起, 氯可穿透金属表面的保护性氧化膜, 加速腐 蚀通过对生物质与煤混燃腐蚀机理的综合分析, 提出了相应的防治措施: ( 1) 加入添 加剂; ( 2) 对燃料进行预处理; ( 3) 在金属表面喷涂耐腐蚀涂层或采用耐腐蚀钢材; ( 4) 调 整运行参数 [ ] 生物质; 煤; 混燃; 碱金属; 腐蚀 [ ] T K 16 [ ] A [ ] 1002-3364( 2011) 05-0035-04 [DOI ] 10. 3969/ j. issn. 1002-3364. 2011. 05. 035 CORROSION IN THE PROCESSOF MIXEDLY BURNINGBIOMASS WITH COAL AND PREVENTIVE MEASURES THEREOF YU E M ozhen, WAN G Yongzheng, BIAN Suf ng, T IA N Sule, LU Chen College of Energy nd Pow er Engineering, Sh ndong University, Jin n 250061, Sh ndong Provin ce, PRC Abstract:T here is l rge content of K nd Cl in biom ss, w hich m y result in severe corrosion on the he ting surf ce of superhe ter in the burning process, limiting l rge-sc le pplic tion of biom ss in therm l pow er pl nts. The technology of mixedly burning biom ss w ith co l c n improve the bove- mentioned problem. In the event the proportion r tio of mix edly burning biom ss is lower, the corro- sion mech nism is simil r to th t of burning co l, the corrosion is m inly c used by sulfuriz tion nd ox id tion in c se of proportion r tio of biom ss is higher , the corrosion is m inly c used by KCl, nd the chlorine m y penetr te the oxide protective film, to cceler te the s id corrosion. T hrough compre- hensive n lysis of the corrosion mech nism in mix edly burning biom ss w ith co l, corresponding pro- tective me sures h ve been