氧化石墨增容不相容共混物Nylon6%2fPVDF研究.pdfVIP

氧化石墨增容不相容共混物Nylon6/PVDF的研究 杨静晖 冯晨霞 戴剑 黄婷 张楠 王勇 西南交通大学材料科学与工程学院，成都，610031 本论文充分利用氧化石墨烯(GOs)的双亲特性[1,2]，探索了氧化石墨烯作为新型的高效 增容剂实现不相容共混物增容的可能性。本论文将氧化石墨烯通过熔融共混的方法引入到尼 龙6(Nylon6)/聚偏二氟乙烯(VDDF）(质量比90/10)体系中，研究结果显示仅仅加入lwt％ 的氧化石墨烯，PVDF相的平均尺寸从约400nm降低至约200nm（图1），且相区尺寸分布 变窄了一半；动态力学分析(DMA)结果也显示，随着氧化石墨烯的加入，PVDF相区尺寸的 减小使PVDF的力学内耗峰被抑制而Nylon6的玻璃化转变温度(Tg)则向低温偏移，这一 现象意味着氧化石墨烯实现了对不相容共混物Nylon6/PVDF的增容。为了更进一步研究氧 化石墨烯的增容机理，分别利用红外光谱分析(FTIR）和拉曼光谱分析(Raman)探究氧化石墨烯 与Nylon6和PVDF之间可能存在的相互作用。 CompatibilizationofImmiscibleNylon6/PVDFBlendUsing GrapheneOxides YANGJinghui1FENGChenxiaDAIJianHUANGtingZHANG NanWANG Yong 1.DepartmentofMaterialScienceandEngineering,SouthwestJiaotongUniverity,Chengdu 610031 Abstract:Inthiswork,anewstrategytocompatibilizeimmiscibleblendswasproposedbyusing grapheneoxides(GOs)nanosheetstakingtheadvantageoftheiruniqueamphiphilicstructures. When0.5wt％ or1wt％ GOswereincorporatedinimmiscibleNylon6/Poly(vinylidenefluoride) (PVDF)(90/10wt％)blends,thedimensionofPVDFdispersedparticleswasdramaticallyreduced andbecamemoreuniform,revealingawell-definedcompatibilizationeffectofGOsonimmiscible blends.Correspondingly,theductilityofcompatibilizedblendsincreasedbyseveraltimes comparedwithuncompatibilizedimmiscibleblends.Inordertoexploretheunderlying compatibilizationmechanism,FTIRandRamanspectrawereappliedtosuggestthattheedged polargroupsofGOscanformhydrogenbondingwithNylon6whilethebasalplanarofGOscan interactwithelectron-withdrawingfluorineonPVDFchainstoobtaintheso-calledcharge-transfer C-Fbonding.Inthiscase,GOsexhibitsuchfavorableinteractionswithbothNylon6andPVDF phase,thereforeitcanbestabilizedattheinterfaceduringGOsmigrationsfromPVDF/GOs masterbatchtoNylon6phase,whichcanminimizetheinterfacialtensionandfinallyleadto compatibilizationeffects.Obviously,thisworkmayopenabroadprospectforGOstobewi