Ti%2fPbO2电极上丙烯酰胺%2f丙烯酸共聚的电催化性能.pdfVIP

第十二届全国有机分子电化学与工业学术会议论文集 Ti/PbO 电极上丙烯酰胺/丙烯酸共聚的电催化性能 2 张丽琴，梁镇海，李万捷，刘成岑 （太原理工大学化学化工学院 山西 太原030024） 摘要：本文采用热分解和电沉积的方法制备了Ti/PbO 电极，并在Ti/PbO 电极的电催化作用下，在引发剂 2 2 剂硝酸铈胺存在的条件下，成功将丙烯酰胺（AM）和丙烯酸（AA）共同聚合为聚（丙烯酰胺-co-丙烯酸）( P ( AM- co-AA))。利用红外光谱（IR）和循环伏安曲线（CV）讨论了共聚产物和其过程的动力学规律；采用 粘度法测定了共聚产物的分子量；考察了在不同单体配比的条件下电流密度、引发剂浓度对共聚物分子量 和共聚反应单体转化率的影响。结果表明：丙烯酰胺和丙烯酸可以在硝酸铈胺Ce(IV)和电化学催化共同作 用下共聚；在单体配比：n (AM):n (AA)=2.3:1, 电流密度：I=0.125 A·cm-2, 引发剂用量ω(Ce(IV))=0.8% 的条件下制到相对分子质量为6.5×105 的聚（丙烯酰胺-co-丙烯酸），转化率可达到70%。该研究结果为聚 合物合成领域提供了一条新思路。 关键词：电催化聚合；丙烯酰胺；丙烯酸；聚（丙烯酰胺-co-丙烯酸） Electrocatalytic properties of acrylamide and acrylic acid copolymerization on the Ti/PbO2 Electrode ZHANG Liqin, LIANG Zhenhai*,LI Wanjie, LIU Chengcen (College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China) Abstract: The Ti/PbO2 electrode was prepared by the thermal decomposition and electro- deposition method. The acrylamide (AM) and acrylic acid (AA) had been polymerized to the Poly (acrylamide-acrylic acid) on the Ti/PbO2 electrode. The reaction products and kinetics of the process were discussed. The molecular weight of the Poly (acrylamide- acrylic acid) was measured by viscosity method. The product was discussed by infrared spectroscopy (IR) and cyclic voltammetry curves (CV).The influence on concentration of monomer 、current density、and initiator concentration were investigated. The results showed that acrylamide and acrylic acid can be polymerized to Poly (acrylamide-acrylic acid) by electrocatalytic polymerization under the effects of both cerium Ce (IV) and e