氢氧化铁对水中砷地吸附试验研究.pdfVIP

第 4卷 第 5期 供 水技 术 Vol. 4 No. 5 2010年 10月 WATER TECHNOLOGY Oct. 2010 氢氧化铁对水中砷的吸附试验研究 李 杰, 李金成, 李 伟, 李 鹏 (青岛理工大学 环境与市 工程学院, 山东 青岛 266033) : 就氢氧化铁对As()的吸附动力学吸附等温线以及 pH和温度等影响因素进行 了研究结果表明:氢氧化铁对As()的吸附动力学符合 Lagergren二级吸附动力学模型, 其吸附 等温线可用 Langmuir方程很好地描述, 即属于单分子层吸附, 试验得到的饱和吸附量为 9. 09 mg/g; pH值在 4. 1~ 8. 5内, 氢氧化铁对As( )的去除率较高,保持在 70 以上, 超出这 个范围, 氢氧化铁对As()的去除率逐渐降低, pH值为 6. 8左右时, 氢氧化铁对As( )的去除率达到最 高,约为 94. 8 ;随着温度的升高, 氢氧化铁对As( )的吸附率逐渐降低, 在 0~ 25 时, 氢氧化 铁对As( )的去除率保持在 80 以上 : 氢氧化铁; As(); 吸附; 除砷 : TU991. 27 : A : 1673- 9353( 2010) 05- 0017- 04 do:i 10. 3969/j. issn. 1673- 9353. 2010. 05. 005 A dsorp tion of A s ( ) from water by ferric hydroxide Li Jie, LiJincheng, LiWe,i LiPeng (D ep artm ent of E nv ironm ental and M unicpi al Eng ineering, Q ing dao T echnolog ical Un iv ers ity, Qingdao 266033, Ch ina ) Abstract: The adsorption ofAs () using ferric hydroxidewas investigated, concerningwith the adsorption kinetics, adsorption isotherm, influencing factorsofpH and temperature. The result showed that the adsorption ofAs () by ferric hydroxide conformed to the second orderLangmuir adsorption kinetic model, the adsorption isotherm couldbewelldescribedwith theLangmuir equation, thiskind of adsorption was single-module layer adsorption, and the saturation adsorption capacity was 9. 09mg/g. When pH ranged from 4. 1to 8. 5, the removalrate ofAs () maintainedabove70 , beyond this scope the removal ratedecreased. When pH was about 6. 8, the removal rate of As () using ferric hydroxidewas the largest, thatwas94. 8 . W ith the temperature increasing, the removal rate ofAs () was gradually r