TMCSHMDSO混合改性剂对常压制备SiO2气凝胶的影响.pdf

TMCS／HMDSO混合改性剂对常压制备Si02气凝胶的影响／邓凌峰等 · 75· 邓凌峰1，左小荣1，卢 斌2，张丁日2，周 强2 (1 中南大学材料科学与工程学院，长沙410083) 中南林业科技大学材料科学与工程学院，长沙410004；2 摘要 以TEOS为硅源，TMCS／HMⅨ如为混合表面改性剂，采用酸碱两步催化溶胶一凝胶法和常压干燥法制 性剂的改性效果优于单一改性剂，当TMCS体积分数为混合表面改性剂的60％，改性温度为60℃时，制备的Si()2气 凝胶具有较佳的综合性能，密度为o．12139·cm，比表面积高达899．8rn2·g～，孔容为2．856cm3·g。 关键词 si01气凝胶溶胶一凝胶法常压干燥法混合改性 中图分类号：()648 文献标识码：A EffectionofSurfaceModificationofSilica withMixed Aerogels AmbientPressure Modifier(TMCS／HMDSO)at DENG Bin2，ZHANG Lingfen91，ZUOXiaoron91，LU Dingri2，ZHOUQian92 of and South of and (1 MaterialsScience UniversityForestryTechnology，Changsha410004； College Engineering，Central 2 ofMaterialsScienceand South 410083) University，Changsha College Engineering，Central as a acid-base sol AbstractSmca were TE()Srawmate“als using bytwo_step catalyzedgel aerogelsprepared structuresof were methodwith thesurfacemodificationunderambient The TMCS／HMDS()for pressure． samples that mixed of characterizedBET，SE小，IandFT～IR，etc．Theresultsindicatethe modified H10difier by aerogels by thatof volumecontentofTMCSis themixedmodifier TMCS／HMDS0isbetterthan singlemodifier．When 60％of andmodified is60℃，sil