PVP稳定的纳米Au溶胶对葡萄糖液相选择氧化的催化性能.pdf

2010 Chinese Journal of Catalysis Vol. 31 No. 6 文章编号: 0253-9837(2010)06-0661-05 DOI : 10.3724/SP.J.1088.2010.91137 研究论文: 661~665 PVP 稳定的纳米 Au 溶胶对葡萄糖液相选择氧化的催化性能 石玲玲, 刘克增, 邹旭华, 金明善, 索掌怀 烟台大学应用催化研究所, 山东烟台 264005 摘要：采用化学还原法制备了聚乙烯吡咯烷酮 (PVP) 稳定的纳米 Au 溶胶, 这种 Au 溶胶在葡萄糖空气氧化制葡萄糖酸反应中具 有良好的催化性能. 考察了 PVP 加入量和氯金酸前驱液的浓度对反应活性的影响. 紫外-可见吸收光谱和透射电镜分析结果表 明, 含有较小 Au 粒子的 Au 溶胶体系具有较高的催化活性. 当 PVP/Au 质量比为 40, 氯金酸浓度为100 μg/ml 时, 得到稳定的 Au 溶 胶体系具有金粒子尺寸小、分布均匀的特点, 对葡萄糖氧化反应活性高, 葡萄糖的转化率达到 54.4%. 关键词：Au 溶胶催化剂; 聚乙烯吡咯烷酮稳定剂; 葡萄糖; 分子氧; 液相选择氧化 中图分类号：O643 文献标识码：A Selective Oxidation of Glucose in the Presence of PVP-Protected Colloidal Gold Solutions * SHI Lingling, LIU Kezeng, ZOU Xuhua, JIN Mingshan, SUO Zhanghuai Institute of Applied Catalysis, Yantai University, Yantai 264005, Shandong, China Abstract: Colloidal metal gold catalysts were prepared by reducing a base solution of chlorauric acid in the presence of a polyvinylpyrroli- done (PVP) stabilizer. The selective oxidation of glucose to gluconic acid in aqueous solution using molecular oxygen as an oxidant at at- mospheric pressure was studied. The activity of the colloidal gold was measured as a function of the PVP amount and various chlorauric acid concentrations. The highest activity with 54.4% conversion of glucose was obtained at a PVP/Au mass ratio of 40 and a 100 μg/ml chlorauric acid concentration. UV-Visible absorption spectroscopy and transmission electron microscopy results showed that the stable gold colloids contain smaller gold nanoparticles. Adjusting the PVP amount and chlorauric acid c