一种高热稳定性的热释光材料MgSO4：Dy，Mn.pdf

核技术991007 核技术 NUCLEAR TECHNIQUES 1999年　第22卷　第10期　VoL.22　 No.10　1999 一种高热稳定性的热释光材料MgSO 4 :Dy,Mn* 罗达玲 •张纯祥 •邓邹平 •李国桢 •唐 •强 摘要 ••MgSO 4 :Dy,Mn的热释光发光曲线只有一个主剂量峰,采用热释光一般级动力学 方程拟合发光曲线,确定热释光主剂量峰的峰参数和陷阱参数值,测定在0.1-20kGy剂量范 60 围内用不同剂量 Co γ射线照射MgSO :Dy,Mn样品的热释光发光曲线,确定出热释光主 4 剂量峰的平均峰温为～383.1℃,平均激活能为～1.972eV,频率因子的平均值为～ 14 -1 4.294×10 s及动力学级数≈2,并得到MgSO :Dy,Mn在此剂量范围的γ辐射剂量响应, 4 用复合作用响应函数拟合得到的非线性特征参数表明为超线性。还测得MgSO 4 :Dy,Mn 226 对 Ra γ辐射在0.1mGy-0.1Gy剂量范围的线性响应。结果表明,MgSO:Dy,Mn具有高的 4 热稳定性和较宽的剂量响应范围,可能在热释光剂量学中获得应用,如热释光和电子自旋 共振测定年代的年剂量测量,以及较高温度和较高辐射剂量环境下的剂量测量。 关键词 ••热释光,陷阱参数,热稳定性,剂量响应 Thermoluminescence phosphor with high thermal stability MgSO4 •:Dy, Mn • LUO Daling •ZHANG Chunxiang •DENG Zouping •LI Guozhen •TANG Qiang •• (Zhongshan University, Guangzhou 510275) Abstract ••There is only one main dosimetric peak on the thermoluminescence glow curve of MgSO4 •;:Dy,Mn phosphor prepared by co-dopant. The peak parameter and trap parameter of the dosimetric peak were determined by deconvolution of their glow curves with general order kinetics for MgSO :Dy,Mn samples irradiated with 60Co γrays at 4 different dose levels. The mean peak temperature of the dosimetric peak was found at 383.1℃, as the mean activation energy E～1.972eV and the mean frequency-factor ～ 4.294×1014s; with kinetics order •f015b •f003≈2. The TL dose-response to 60Co γrays in the dose range of 0.1Gy •20kGy was obtained and fitted by the composite action dose response function to give the nonlinear characteristic parameters which showed this re