具有MWW结构钛硅分子筛的研究进展.pdfVIP

2010 Chinese Journal of Catalysis Vol. 31 No. 5 文章编号: 0253-9837(2010)05-0502-12 DOI : 10.3724/SP.J.1088.2010.91205 综述(特约) : 502~513 具有 MWW 结构钛硅分子筛的研究进展 谢 伟, 刘月明, 汪玲玲, 吴 鹏 华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室, 上海 200062 摘要：综述了具有 MWW 结构钛硅分子筛的制备方法、孔道和晶体结构的调变和修饰以及催化应用三个方面的研究进展. 与 TS-1 相比, 具有 MWW 结构钛硅分子筛的制备方法多种多样; 其孔道结构可塑性强, 通过采用层间剥离、柱撑以及分子水平硅烷 化插硅扩孔技术, 可以增大和暴露孔道和外表面, 满足不同选择氧化反应的要求. 由于 MWW 结构钛硅分子筛拥有复杂而独特 的孔道结构, 所以在小分子 (如直链烯烃等) 的环氧化反应, 和大分子 (环状烯烃, 二苯并噻吩等) 氧化反应中都表现出优异的催化 性能. 此外, 该钛硅分子筛表现出与 TS-1 完全不同的溶剂效应, 用于烯丙基氯液相环氧化与酮类氨氧化反应主产物选择性更高. 关键词：钛硅分子筛; Ti-MWW 分子筛; TS-1 分子筛; 过氧化氢; 液相氧化 中图分类号：O643 文献标识码：A Recent Advances in MWW-Type Titanosilicates * XIE Wei, LIU Yueming, WANG Lingling, WU Peng Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China Abstract: The progress in the preparation, structure modification, and catalytic applications in liquid-phase selective oxidations of MWW-type titanosilicates is reviewed. A novel titanosilicate with the MWW topology, Ti-MWW, has been prepared by various methods such as hydrothermal synthesis using boric acid as a crystallization-supporting agent, dry gel conversion, postsynthesis through reversible structural conversion, and dual structure-directing agents method. Ti-MWW, originating from a lamellar precursor, is readily subjected to various structural modifications, which leads to the catalytic materials with larger porosity suitable for a variety of oxidations. The unique pore and structure properties of Ti-MW