吸附Cu2+接枝纤维的制备与表征.pdfVIP

吸附Cu“接枝纤维的制备与表征卫威 吸附Cu2+接枝纤维的制备与表征 卫威，石美玲，朱红祥 (广西大学轻工与食品工程学院，广西 南宁530004) 摘要：以漂白蔗渣浆纤维素为基体，二乙烯三胺为单体，硝酸铈铵为引发剂，制备胺基接枝纤维，制备高效重金 属吸附剂。研究了单体用量、引发剂用量、温度、时间等反应因素对胺基接枝纤维制备的影响。采用红外光谱、x射 线衍射和扫描电镜分析表征胺基接枝纤维的结构。结果表明：绝干蔗渣纤维：单体二乙烯三胺=l：l(质量比)，硝酸 铈铵的用量为25％，温度为70℃，时间为2h时可以获得较高的吸附量，其吸附量可以达到12．8mg／g。通过红外 光谱和扫描电镜分析手段，对接枝纤维的结构进行表征。 关键词：接枝共聚；纤维改性；吸附；Cu“；铜离子捕捉剂 中图分类号：X83 文献标志码：A andCharactedzationofGraftFiberAdsorbedlons Preparation Copper Wei Wei，Shi Meiling，ZhuHongxiang of IndustrialandFood Light University，Nanning530004，China) (College Ensnaring，Guangxi and纠[nnlonium celluloseas triamineasmonomer cerium Abstract：Usingbleachingbagassepulp substrate，diethylene nitrate to fiberandefficientmetals influencesofmonomer asinitiator adsorbent，the prepareamino-grafted heavy dosage，initiator andotherfactorsonthe of fiberwere structureofamino— dosage，temperature，time preparationamino—grated investigated．r11Ie fiberWascharacterizedF-11R diffractionand electron resIlltsshowed grafted by spectra,x—my scanning microscopeanalysis．，IIle thatmassratioofovendried fiberandmonomer triamine ofammoniumcericnitratewas wasl：l，the 25％， hgasse diethylene dosage couldreceive for ionsof12．8 Was70℃，timeWas2hours，which temperature