样品位置对碳材料XRD测试结果的影响.pdfVIP

RD 李同起 杨晓光 许正辉 孙银洁 王晓叶 (, 100076) 为研究样品测试表面位置对碳材料 RD衍射 特征和微结构的影响, 采用 H- H模式运行的 射线衍射仪对块状中间相沥青基碳材料进行了表征,并分析了测试样品表面高低对 RD衍射 形和碳材料 微结构参数的影响结果表明: 测试样品表面位置对碳材料的衍射 形和碳材料微结构参数产生很大影响, 主要表现为衍射 强度显著降低 位置有较大偏移 半高宽有较大变化, 造成了根据这些参数计算的碳材 料微结构参数有较大变化这些影响与 射线衍射仪的工作原理有关, 因此在利用 RD测试样品时需要严 格控制样品表面在标准测试位置上 碳材料, RD,微结构, 测试面位置, 形特征 Influence ofTesting Position on RD Results of CarbonMaterial LiTongqi Yang iaoguang u Zhenghui Sun Y injie W ang iaoye (NationalKey Laboratory ofAdvanced FunctionalCompositeM aterials, AerospaceResearch Institute ofM aterials Processing Technology, Beijing 100076) Abs tract In order to clarify the influence of the tested surface altitudeon the RD peak features and them icro- structure parameters of carbon material, an - ray diffractom eter, working in themodeofH- H, was used to charac- terize a bulkmesophase pitch-based carbonmateria.l Itwas found that the tested surface altitudepossessed significant influence on the RD peak features and them icrostructure param eters of carbonm aterial. For example, the intensity of diffraction peak decreased obviously, the position of diffraction peak shifted to a large degree and w idth at half height of the peak changed greatly. These changes in peak features further caused the large variation in them icro- structure parameters. These changes in peak features occurred on - ray diffractometersdue to their inherentworking mechanism. Therefore, the surfaces of samplesmust be placed on the standard levels during testing. K ey w ord s Carbon materia,l RD, M icrostructure, Tested surface level, Peak features 1 , ( d002 RD L c L a ) RD( 00210 [ 1~ 3] ),