Influence of the crystalline phase and surface area of the TiO2 support on the CO oxidation activity of mesoporous Au TiO2 catalysts外文翻译.pdfVIP

Applied Catalysis B: Environmental 91 (2009) 470–480 Contents lists available at ScienceDirect Applied Catalysis B: Environmental journal h omepage: www.else /locate/apcatb Influence of the crystalline phase and surface area of the TiO2 support on the CO oxidation activity of mesoporous Au/TiO2 catalysts a a b ¨ c c c ¨ b a,* Y. Denkwitz , M. Makosch , J. Geserick , U. Hormann , S. Selve , U. Kaiser , N. Husing , R.J. Behm a Institute of Surface Chemistry and Catalysis, Ulm University, D-89069 Ulm, Germany b Institute of Inorganic Chemistry I, Ulm University, D-89069 Ulm, Germany c Central Facility of Electron Microscopy, Ulm University, D-89069 Ulm, Germany A R T I C L E I N F O A B S T R A C T Article history: The influence of the TiO2 crystalline phase and of the surface area on the activity and stability/ Received 13 March 2009 deactivation behavior of structurally well-defined mesoporous Au/TiO2 catalysts with comparable Au Received in revised form 15 June 2009 loading in the CO oxidation reaction was investigated by kinetic measurements under differential Accepted 18 June 2009 reaction conditions and by in situ DRIFTS. The crystalline phase and surface area of the TiO2 substrate Available online 24 June 2009 were controlled by the pH and the type of the structure-directing su