渣油芳香烃复合树脂及聚乙烯复合材料研究.pdf

石油学报(石油加工) 2009年8月 ACTAPETROLEISINICA(PETROLEUMPROCESSINGSECTION) 第25卷第4期 文章编号：1001—8719(2009)04—0564—06 渣油芳香烃复合树脂及聚乙烯复合材料研究 李京子，柯扬船，王英年，范颜晓 (中国石油大学重质油国家重点实验室，北京102249) 摘要：以渣油萃取富芳香馏分为单体，苯甲醛为交联剂，对甲苯磺酸为催化剂，合成软化点为110℃、残炭率约为 粒，该复合颗粒耐140C热老化，并具有更高增强性能，以其作为分散相，与聚乙烯熔融共混制备复合材料，其力学 断裂伸长率和弯曲强度均有提高。电镜分析表明，“核一壳”复合颗粒较均匀分散于聚乙烯摹体形成新颖的空洞化形态。 关 键 词：渣油；多核芳烃混合树脂(b—COPNA)；“核一壳”颗粒；聚乙烯复合材料 中图分类号：TQ326文献标识码：A ARoMATlC STUDYONRESIDUACONDENSEDPoLYNUCLEARCoMPOSITE RESINSANDTHEIRPoLYETHYLENECoMPOSlTEMATERIAL LI Yan—xiao Jing—zi，KEYang—chuan，WANGYing—nian，FAN China (State OilProcessingt UniversityPetroleum，Beijing102249，China) KeyLaboratoryofHeavy of as monomerwasused residuaoilwasextracted．Theobtainedaromaticfractionationreactive Abstract：The to reactionunderthe as and poly—condensation benzaldehydecross—linkingagent nucleararomatic B acidas condensed resins(b—COPNA)of catalyst．Theblending poly stagepitch wereobtainedwiththeresinssoft of110℃andresidualcarbonof60％orso．Theseresins point wereusedto the of and nanoparticlesSi02，CaC03 encapsulate toformcore-shellstructured thermal wastO140℃ respectively compositeparticles．Itsstabilityup andits wasenhanced．As core—shell were performance dispersionphase，the compositeparticles mixedwith resins the