胺复合物合成形貌可控金纳米结构.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 1026 A cta Phys. Chim. Sin., 2009, 25(5) 1026-1032 May [Invited Review] 基于AuCl(油胺)复合物合成形貌可控的金纳米结构 马艳芸 曾 杰 夏幼南* (Department of Biomedical Engineering, Washington University, Saint Louis, Missouri 63130, USA) 摘要 简要综述了使用一价金复合物AuCl(油胺)作为前驱物合成形貌可控的金纳米结构的相关工作. 通过改 变有机溶剂、添加异质金属纳米粒子及控制反应温度等手段, 成功合成出球形的金纳米粒子(平均直径 12.7 nm) 、超细金纳米线(平均直径 1.8 nm)及超细金纳米棒(平均直径2 nm); 并通过牺牲磁性纳米粒子模板的方法合 成出枝状金纳米结构. 除了对合成方法和过程的介绍, 还简要讨论了每种纳米结构的形成机制. 关键词 ：金; 纳米结构; AuCl(油胺)复合物 中图分类号 O641.4; O647; O614.12 Synthesis of Gold Nanostructures with Controlled Morphologies from AuCl(Oleylamine) Complex MA Yan Yun ZENG Jie XIA You Nan* (Depa rtment of Biomedical Engineering, Washington University, Saint Louis, Missouri 63130, USA) Abstract This review article briefly discusses the use of AuCl (oleylamine) complex as a precursor in the facile synthesis of gold nanostructures with controlled morphologies. By controlling the solvent, the added metal nanoparticles, and the reaction temperature, we have successfully prepared spherical gold nanoparticles with an average diameter of 12.7 nm, ultrathin gold nanowires with an average diameter of 1.8 nm, and ultrathin gold nanorods with an average diameter of 2 nm. Gold multipod nanostructures have also been prepared by templating against a self destructive template of magnetic nanoparticles. In addition to the synthetic protocols, this article also provides a brief account of the mechanism responsible for forming each type of gold nanostructure. Key Words Gold; Nanostructure; AuCl(