超高相对分子质量聚乙烯纤维的表面改性研究.pdfVIP

35 5 Vol.35 No.5 第 卷 第 期 高科技纤维与应用 2010年10月 Hi-Tech Fiber Application Oct. 2010 超高相对分子质量聚乙烯纤维的表面改性研究 1,2 1,2 1,2 1,2 1,2 1,2 邝金艳 ，南建举 ，于俊荣 ，胡祖明 ，陈 蕾 ，诸 静 ( 1. 东华大学 高性能纤维及制品教育部重点实验室，上海 201620；2. 东华大学 纤维材料改性国家重点实验 室，上海 201620 ) 摘 要:选择乙烯-醋酸乙烯酯共聚物作为表面改性剂，将其溶解在二甲苯中制成复合萃取液，对超高相对分子质量聚乙烯 UHMWPE UHMWPE （ ）冻胶纤维进行萃取，经干燥和超倍拉伸制得表面改性 纤维。对改性前后纤维的表面化学结构、结晶性 能、表面粘接性能和力学性能进行了比较。结果表明：加入表面改性剂后，纤维表面引入了极性基团，结晶形态不变，纤维 与树脂的抗界面剪切强度大大增加，纤维的力学性能变化不大。 关键词:超高相对分子质量聚乙烯纤维；表面改性；粘接强度；研究 中图分类号: TQ342.61 文献标识码: A 文章编号: 1007-9815 2010 05-0051-05 （ ） Study on the Surface Modification of Ultra-high Molecular Weight Polythylene Fiber KUANG Jin-yan1,2, NAN Jian-ju1,2, YU Jun-rong1,2, HU Zu-ming1,2, CHEN Lei1,2, ZHU Jing1,2 ( 1. Key Laboratory of High-performance Fibers Products, Ministry of Education, Donghua University, Shanghai 201620 China; 2. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620 China ) Abstract: Ethylene/vinyl acetate copolymer (EVA) was selected as surface modifiers and dissolved in xylene to make complex extraction solvent. The modified ultra-high molecular weight polyethylene(UHMWPE) fibers were made after the gel fiber extracted with the complex solvent and followed by drying and subsequent multi-step hot drawing. The surface chemical structure, the crystallizing properties, as well as interfacial adhesive properties and mechanical properties of the original and the modified UHMWPE fi