中孔石墨碳负载TiO2复合材料光催化降解罗丹明B和苯酚肖义.pdfVIP

29 1 2008 1 Vol.29 No.1 ChineseJournal of Catalysis January 2008 :0253-9837 2008 01-0031-06 :31～36 TiO B 2 1 1 1 1 1, 2 肖　义 , 　党利琴, 　安丽珍 , 　白士英, 　雷志斌 1 辽宁师范大学化学化工学院功能材料化学研究所, 辽宁大连 116029; 2 建省光催化重点实验室-省部共建国家重点实验室培育基地, 建 州350002 2 :26 nm SiO , , Ni , 950 ℃298.2 m /g 2 .X 、 N 、., Ni 2 , .- TiO , TiO / 2 2 .B , TiO /., 2 , B , B TiO . 2 :;;;B;; :O643　　　:A Photocatalytic Degradation of RhodamineB andPhenol by TiO2 Loaded onMesoporous Graphitic Carbon 1 1 1 1 1, 2 ＊ XIAO Yi , DANG Liqin , AN Lizhen , BAI Shiying , L EI Zhibin 1 Institute of Chemistry f or Functionalized Materials, Faculty of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 1160 9, Liaoning, China; S tate K ey L aboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 35000 , Fuj ian, China 2 Abstract:Mesoporous graphitic carbon with high surface area 298.2 m /g was fabricated at 950 ℃using monodisperse colloid SiO2 with diameter of 26 nm as the template, styrene as the carbon precursor, and Ni as the catalyst.The obtained carbon material was characterized by powder X-ray diffraction, N adsorption, ther- 2 mogravimetric analysis, and transmission electron microscopy.The presence of Ni was crucial to the formation of graphitized mesoporous carbon.The TiO /graphitic carbon composite was prepared by loading TiO in the 2 2 mesopores of the graphitic carbon via the sol-gelmethod.Both the surface area and pore volumeof the composite were significantly reduced in contrast to the mesoporous graphitic carbon.The photoactivity of TiO2/graphitic carbon was investigated by photocatalytic degradation aqueous solutions of rhodamine B and phenol.The degra- dation of both rhodamine B and phenol followed first-order reaction kinetics, and the composite showed higher photoactivity than the pure anatase TiO . 2 ey words:mesoporous carbon;catalytic graphitization;titania;rhodamine B;phenol;photodegradation , , ,、、、 [7～9] . [1～6] . , :2007-06-18.　:　, , 1981 , .