5_羟甲基糠醛在稀硫酸催化下降解反应动力学_彭新文.pdfVIP

59 5 V ol1 59 N o1 5 2008 5 J ournal o f Chem ical Indu stry and Eng ineering ( China) M a y 2008 5- 彭新文, 吕秀阳 ( 3 10027) : 5- 5 M Pa 1~ 9 mg # ml- 1 01 05 % ~ 01 4% ( ) 150~ 190 e 5- 5- ; H+ 11 16 781 5 kJ # mol- 1 ; H + 01 7 22 981 0 kJ # mol- 1 : 5- ; ; ; ; : T Q 032; O 6431 12 : A : 043 8- 1157 ( 2008) 05 - 1150 - 06 Decomposit ion kinetics of 5- hydroxymethylfurfural catalyzed by dilute sulfuric acid PENG Xinwen LB Xiuyang ( National L aboratory of Secondary Resources Chemical Eng ineering Zhej iang University H angz hou 310027 Zhej iang China) Abstract: T he decarbo xy lat ion o f 5- hy drox ym et hylf urfural t o levulinic acid is a key step in t he prep ar at ion of levulinic acid f rom biom as s1 In order t o st u dy the feasibility of pro du cing levulinic acid by hydroly zing biom as s w ith dilute sulfuric acid t he decomposit ion kinet ics o f 5- hy dro xym et hylf urfural w as - 1 syst em at ical ly invest igat ed at init ial 5- hydrox ymet hylf urf ural concentr at ion of 1 ) 9 m g # m l sulf uric acid concent rat ion o f 0105% ) 014% ( m as s) and temp erat ure f rom 150 e to 190 e 1A