加氢脱硫2010_Wan-G._Gao-Z._Catal-Today_Zeolite-beta-synthesized-with-acid-treated-metakaolin-and-its.pdfVIP

Catalysis Today 149 (2010) 69–75 Contents lists available at ScienceDirect Catalysis Today journal homepage: www.els /locate/cattod Zeolite beta synthesized with acid-treated metakaolin and its application in diesel hydrodesulfurization Guofu Wan a,b, Aijun Duan a,*, Ying Zhang c, Zhen Zhao a,*, Guiyuan Jiang a, Dengqian Zhang a, Zhenyong Gao a a State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, PR China b College of Mechanical and Energy Engineering, Jiangsu Polytechnic University, Changzhou 213016, PR China c Department of Materials Science and Engineering, University of Petroleum, Beijing 102249, PR China A R T I C L E I N F O A B S T R A C T Keywords: A new type of zeolite beta (denoted as MB) with multi-pore system was synthesized by using in situ Hydrodesufurization synthesized method from kaolin mineral in this study. NiW/Al O –MB and NiW/TiO –Al O –MB 2 3 2 2 3 FCC diesel catalysts were prepared and the hydrodesulfurization (HDS) activities of these catalysts were evaluated Zeolite beta with FCC diesel feed. The samples were characterized by N2 physisorption, XRD, SEM, TPR, FT-IR Kaolin spectroscopy of pyridine adsorption, HRTEM and XPS techniques. The HDS results showed that the MB- In situ synthesized metho