Pseudo-quinary Ti20Zr20Hf20Be20(Cu20 -xNix) high entropy bulk metallic glasses with large glass forming ability》.pdf

Materials and Design 87 (2015) 625–631 Contents lists available at ScienceDirect Materials and Design journal homepage: www. /locate/jmad Pseudo-quinary Ti Zr Hf Be (Cu Ni ) high entropy bulk metallic 20 20 20 20 20-x x glasses with large glass forming ability S.F. Zhao, Y. Shao, X. Liu, N. Chen, H.Y. Ding, K.F. Yao ⁎ School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China a r t i c l e i n f o a b s t r a c t Article history: A series of pseudo-quinary Ti Zr Hf Be (Cu Ni ) (x = 2.5, 5, 7.5, 10, 12.5, 15, 17.5 and 20 at.%) high entropy 20 20 20 20 20-x x Received 5 May 2015 bulk metallic glasses (HE-BMGs) with large glass forming ability (GFA) were successfully prepared by copper Received in revised form 2 August 2015 mold tilt-casing. The critical diameters (Dc) of these HE-BMGs are all above 12 mm. In particular, the developed Accepted 16 August 2015 Ti20Zr20Hf20Be20 (Cu7.5Ni12.5) and Ti20Zr20Hf20Be20Ni20 high entropy alloys (HEAs) can be produced in the Available online 22 August 2015 amorphous state with diameters up to 30 mm and 15 mm, respectively, which are the largest HE-BMG and Keywords: quinary HE-BMG hitherto. The two HE-BMGs also exhibit high yi