Quasi-one-dimensional (Q1D) organic Mott insulators based on bent donor molecule EDO-EDSe-TTFVS》.pdf

Synthetic Metals 162 (2012) 2342–2348 Contents lists available at SciVerse ScienceDirect Synthetic Metals j o u rn a l h o me p a g e : w w w. elsev /locate/syn met Quasi-one-dimensional (Q1D) organic Mott insulators based on bent donor molecule EDO-EDSe-TTFVS Shangxi Zhang a , Jiafeng Shao b , Jibin Sun a , Guiyang Jiang a , Yali Zhao a , Zili Cui a , Jinlian Zhao a , Xiangfeng Shao a,∗ a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, Gansu Province, PR China b School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, Gansu Province, PR China a r t i c l e i n f o a b s t r a c t Article history: A series of conducting quasi-one-dimensional (Q1D) cation radical salts based on a bent donor molecule Received 9 October 2012 EDO-EDSe-TTFVS (1), 12 ClO , 1 PF (PhCl) , and 1 AsPF (PhCl) , were obtained via electrocrystalliza- 4 2 6 0.25 2 6 0.25 Received in revised form tion. These salts show the semiconducting behavior with moderate conductivities up to 4.0 S cm−1 and 21 November 2012 −4 −1 relatively large magnetic susceptibilities of 9 × 10 emu mol . The temperature dependent magnetic Accepted 23 November 2012 Available online 20 December 2012 susceptibilities of these salts can be well fitted by the one-dimensional Heisenberg a