Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors》.pdf

Journal of Power Sources 270 (2014) 675 e683 Contents lists available at ScienceDirect Journal of Power Sources journal homepage: /locate/jpowsour Rational design of hierarchically porous birnessite-type manganese dioxides nanosheets on different one-dimensional titania-based nanowires for high performance supercapacitors Yu Xin Zhang a, b, *, Min Kuang a, Xiao Dong Hao a, Yan Liu c, d, **, Ming Huang a, Xiao Long Guo a, Jing Yan c, d, Gen Quan Han c, d, Jing Li e a College of Materials Science and Engineering, Chongqing University, Chongqing 400044, PR China b National Key Laboratory of Fundamental Science of Micro/Nano-Devices and System Technology, Chongqing University, Chongqing 400044, PR China c Key Laboratory of Optoelectronic Technology and Systems of the Education Ministry, Chongqing University, Chongqing 400044, PR China d College of Optoelectronic Engineering, Chongqing University, Chongqing 400044, PR China e Department of Chemistry, Tongji University, Shanghai 200092, PR China h i g h l i g h t s g r a p h i c a l a b s t r a c t MnO2 nanosheets were decorated on 1D TiO2 nanowires by a facile and large-scale method. The MnO2/TiO2 coreeshell architec- ture exhibited a high capacitance of 120 F g1 (0.1 A g1). Excellent cycling stability: 93% capacitance retention after 3000 cycles. The asymmetric supercapacitor yiel- ded a maximum energy density of 1 29.8 Wh kg . a r t i c l e i n f o a b s t r a c t Article history: A facile and large-scale strategy of mesoporous birnessite-