新型芳氧基稀土单组分催化剂催化内酯和交酯开环聚合的研究.pdfVIP

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新型芳氧基稀土单组分催化剂催化内酯和交酯开环聚合的研究.pdf

of£一caprolactone and Homopolymerizations tris earth block ofCLwithLLA rare single L—lactide(LLA)and by copolymerization forthefirst effectsof have carriedout time.The been (2,6-dimethylphenolate)s onthe aswellasthekineticsofsolution reactionconditionspolymerization andDLLAwith were ofCL La(ODMP)3intensively polymerization ring—opening examined.Protonandcarbon.13nuclear resonance(1H/13C magnetic NMR)and used the andto infrared tocharacterize structuralfeatures spectrum(IR)are polymer’S the mechanism. studypolymerization Therareearth were and tothe tris(2,6-dimethylphenolate)ssynthesizedapplied ofCLandDLLA rare andthe of earth homopolymerizationsrespectively.Thestudy ofsolventshowthat exhibitsthe to higher polarity La(ODMP)3highestactivitygive monomerconversionand with molecularin solvents. polymer higher weightnonpolar ThecharacteristicsofCLandDLLA were polymerizationcatalyzedbyLa(ODMP)3

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