细乳液中RAFT活性聚合弹性体材料的制备和性能的研究.pdf

摘要 Abstract Inthis chaintransferwereusedto well．definednovel paper，6 agent synthesis AB diblock and4ABAtriblock copolymers．2 of type copolymers type copolymers and innanoreactorof styrenen-butyl miniemulsion acrylate(BA)wereprepared using reversible chain structure addition—fragmentation ofthe were characterized molecularandmolecular copolymers FT．IR，the by weight distributionwere weight characterizedGPC by analysis，thedynamiclightscattering usedtocharacterizethesizeofthe (DLS)was nanoparticle．Thebreakingstrength， andother elongationmechanicalweremeasuredtoo． properties chaintransferBSSEand (1)The agent DCATCwereused to respectively preparestyrene，styrene／maleic inminiemulsion styrene／methyl and followed methacrylate(MAA)copolymer they theruleofthe radical PSminiemulsion living wasusedas polymerization．Then，the seed thesecond monomer for24hoursandAB emulsion，adding BA，swelling type WaS formed intheRAFT copolymer successfully miniemulsion