《New secondary batteries and their key materials based on the concept of multi-electron reaction.》.pdf

《New secondary batteries and their key materials based on the concept of multi-electron reaction.》.pdf

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《New secondary batteries and their key materials based on the concept of multi-electron reaction.》.pdf

Chin.Sci.Bul1.(2014)59(27):3369——3376 csb.scichina.com D0I10.1007/sl1434—014—0430—3 www.springer.com/scp New secondarybatteriesandtheirkeymaterialsbased on theconceptofmulti·electron reaction FengW u ‘ChuanW u Received:25December2013/Accepted:10February 2014/Publishedonline:20M ay2014 ◎ ScienceChinaPressandSpringer—VerlagBerlinHeidelberg2014 Abstract Facing the significantapplicationsin energy secondraybatterieshavebecomean internationalhotspot field,thispaper introduceshow to constructnew high in relatedreserach field.Asan efhcient.reusableenergy specificenergysecondarybatteriesbased on theconcept conversionandstorageway,secondarybattery hasbecome multi--electron reaction and by designing multi..electron thecrucialfactorinaseriesofmajorhigh..techdevelop.. electrode materials.Recentprogresson thosenew sec. ments.Ithasbecomean importanttechnicalapproachto ondarybatteriesandtheirkeymaterialsbasedonthetheory easetheenergY,resourcenadenvironmentalproblems,as ofmulti—electronreactionareoverviewed.Representative wellasakeylinkofphotovoltaicenergystoragesystems, multi-electronicelectrodematerials。suchasmetalborides. electricvehicles,Peak LoadModulation plants,uninter。 metalfluorides,sulfurcompositeelectrodematerialsand ruptiblepowersupplyandothersignificantapplications.As ferratesarebrieflyintroduced.aswel1asthenew secondary amajorworkingpowerinthePortableEra,secondary battery systemsconstructed with these materials.Thus battery hasalready been listedassupporthighlightsby givesthesignificanceofthedevelopmentbasedonmulti— many developed countries.However.the currentengi. electron reaction mechanism ofsecondary batteriesand neeringlevelsofthesecondarybatteries,especially inthe theirkeymaterialsfornew chemicalbattery syst

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